EVALUATION OF SOME THICK FILM MATERIALS FOR
TEMPERATURE, FORCE, AND HUMIDITY SENSORS
M. HROVAT, D. BELAVIC*, J. HOLe
loief Stefan Institute, lamova 39, 61000 Ljubljana, Slovenia
* Iskra HIPOT, Trubarjeva 7, 68310 Sentjemej, Slovenia
1. Introduction
Thick film technology is a well known, mature and versatile technology for producing
hybrid circuits. Also, for some applications it provides a relatively inexpensive and
convenient way to produce sensors which can be integrated in to hybrid circuits. The aim
of this paper is to present some results obtained with commercial thick film pastes for
temperature and strain sensors (thick film conductors and resistors, respectively), and
results on thick film humidity sensors based on Nb205 doped Ti02.
2. Temperature sensors
Thermocouples were made with different combinations of thick film conductors based
on Ag, Au, AulPd, AuIPt, AglPd, AgIPt, Ni and Cr, printed and fired on alumina substrates.
Noble metal based pastes (Du Pont) were frred at 850°C, while air-frring Ni and Cr pastes
(Electro Science Labs.) were frred at 750°C. Absolute EMFs (at 25°C) and nonlinearity
(dependence of thermocouple EMF on temperature) are presented in Table 1[1,2].
Table I: Absolute EMF and nonlinearity of thick film thermocouples
Conductor EMF (25 "C) Nonlinearity Conductor EMF (25 0c) Nonlinearity
combination b.tVIK) [o/crIK] combination [J.1VIK) [o/crIK]
AulPd-Au 16.85 0.24 AulPd-AglPd 8.29 0.35
AglPd-Au 6.62 0.22 AuJPt-AglPd 2.38 0.18
AulPd-Ag 14.41 0.22 AuJPt-Au 10.75 0.13
AuJPt-Ag 9.06 0.24 AuJPt-AulPd 6.61 0.08
Au-Ag 0.04 ? AgIPt-Ag 1.49 -0.Q7
Ni-Cr 13.65 - 0.22 AglPd-AglPt 5.48 0.13
AglPd-Ag 6.15 0.21
The prototype of a thick film heat flux sensor with 110 thermocouples, connected in
series, was designed [1]. Heat flux sensors, realized in thick film technology have some
good characteristics, for example low thermal resistivity and relatively high operating
temperatures [3,4]. The thermal resistance layer is made of thick film multilayer dielectric
pastes, printed and frred on Ah03 substrates. Multilayer dielectrics are glass-like materials
with higher heat resistivity than alumina substrates. The heat flow is perpendicular to the
ceramic substrate. The temperatures on the top (cold junction) and underneath (hot
267
W. K. Jones et al. (eds.). MCM ClMixed Technologies and Thick Film Sensors. 267-272.
© 1995 Kluwer Academic Publishers.