Available online at www.sciencedirect.com
ScienceDirect
Materials Today: Proceedings 7 (2019) 920–929
www.materialstoday.com/proceedings
2214-7853 © 2018 Elsevier Ltd. All rights reserved.
Selection and/or peer-review under responsibility of NanoFIS 2017 - Functional Integrated nano Systems.
NanoFIS 2017
Novel Nanoporous Carbon/Iron Oxide Catalyst for SO
2
Degradation
Maja Stanisavljević
a
, Savka Janković
a
, Dragana Milisavić
a
, Marko Čađo
b
,
Zoran Kukrić
b
, Dragana Stević
c
, Radovan Kukobat
c
, Predrag Ilić
d
, Denis Međed
d
,
Magdalena Parlinska Wojtan
e
and Suzana Gotovac Atlagić
a
*
a
Faculty of Natural Sciences and Mathematics, University of Banja Luka, Mladena Stojanovića 2, Banja Luka 78000, Bosnia and Herzegovina
b
Faculty of Technology, University of Banja Luka, Bulevar vojvode Stepe Stepanovića 73, Banja Luka 78000, Bosnia and Herzegovina
c
Center for Energy and Environmental Science,Shinshu University, Wakasato 4-17-1, Nagano 380-8553, Japan
d
Institute for Protection and Ecology of the Republic of Srpska, Vidovdanska 43, Banja Luka 78000, Bosnia and Herzegovina
e
Institute of Nuclear Physics, Polish Academy of Science, Krakow PL-31-342, Poland
Abstract
A green chemistry approach for fabrication of active carbon, enriched with remediated iron is shown. Detailed characterization
(HRSTEM, STM, and N
2
adsorption) was performed, followed by active carbon soaking in iron and manganese ionic solutions
obtained from remediated mining sludge. Novel forms of active carbons with round or needle-like oxide particles on the surface
were obtained by combining these materials. The materials were tested as filters for sulfur dioxide, on sulfur-rich coals fume.
After adsorption, the iron structures seem to play a stronger catalytic role in the filter regeneration, transforming the adsorbed
sulfur dioxide into sulfuric acid.
© 2018 Elsevier Ltd. All rights reserved.
Selection and/or peer-review under responsibility of NanoFIS 2017 - Functional Integrated nano Systems.
Keywords: active carbon; mining sludge; metal remediation; organometallic materials; SO
2
filtration
1. Introduction
In today’s society high demand and consumption of energy has caused serious pollution of air, soil and water.
The sources of pollution are fossil fuels, industries, traffic, agriculture and many other human activities, but
regardless of its origin the consequences of human reluctant behavior are getting more and more apparent as well as
* Corresponding author. Tel.: +387-51-319-142; fax: +387-51-319-142.
E-mail address:suzana.gotovac.atlagic@unibl.org