Precision Agric
https://doi.org/10.1007/s11119-018-9579-0
1 3
Development of feld mobile soil nitrate sensor
technology to facilitate precision fertilizer management
Natalia Rogovska
1
· David A. Laird
1
· Chien‑Ping Chiou
2
· Leonard J. Bond
2
© Springer Science+Business Media, LLC, part of Springer Nature 2018
Abstract Precision nitrogen (N) fertilizer management has the potential to improve N
fertilizer use efciency, simultaneously reducing the cost of inputs for farmers and the of-
site environmental impact of crop production. Although technology is available to spatially
vary sidedress N fertilizer application rates within felds, sensor technology capable of
measuring soil nitrate (NO
3
−
) levels in-real-time and on-the-go with sufcient accuracy to
facilitate precision application of N fertilizers is lacking. The potential of Diamond-Atten-
uated Total internal Refectance (D-ATR) Fourier Transform Infrared (FTIR) spectroscopy
was evaluated as a soil NO
3
−
sensor. Two independent datasets were tested; (1) the feld
dataset consisted of 124 GPS registered soil samples collected from four agricultural felds;
and (2) the laboratory dataset consisted of fve diferent soils spiked with various amounts
of KNO
3
(135 samples) and incubated in the laboratory. Spectra were collected using an
Agilent 4100 Exoscan FTIR spectrometer equipped with a D-ATR cell and analyzed using
partial least squares regression. Calibration R
2
values (D-ATR-FTIR predicted versus inde-
pendently measured soil NO
3
−
concentrations) for the feld and laboratory datasets were
0.83 and 0.90 (RMSE = 8.3 and 8.8 mg kg
−1
), respectively; and robust “leave one feld/
soil out” cross validation tests yielded R
2
values for the feld and laboratory datasets of
0.65 and 0.83 (RMSE = 12.5 and 13.3 mg kg
−1
), respectively. The study demonstrates the
potential of using D-ATR-FTIR spectroscopy for rapid feld-mobile determination of soil
NO
3
−
concentrations.
Keywords Soil nitrate sensor · Late spring nitrate test · Variable rate N fertilization ·
On-the-go nitrate sensing · Fourier Transform Infrared spectroscopy
* David A. Laird
dalaird@iastate.edu
1
Department of Agronomy, Iowa State University, Ames, IA 50011, USA
2
Center for Nondestructive Evaluation, Iowa State University, Ames, IA 50011, USA