Vol.:(0123456789) 1 3
Journal of Materials Science: Materials in Electronics
https://doi.org/10.1007/s10854-018-9572-4
Signifcance of encapsulating organic temperature sensors
through spatial atmospheric atomic layer deposition for protection
against humidity
Mohammad Mutee ur Rehman
1
· Muhammad Muqeet Rehman
2
· Memoon Sajid
1,3
· Jae‑Wook Lee
1
·
Kyoung Hoan Na
4
· Jeong Beom Ko
5
· Kyung Hyun Choi
1
Received: 30 March 2018 / Accepted: 27 June 2018
© Springer Science+Business Media, LLC, part of Springer Nature 2018
Abstract
Printed organic sensors are of signifcant importance owing to their simplicity, low cost, easy fabrication and solution pro-
cessability. However, organic sensors often face the problem of performance degradation when exposed to ambient environ-
ment therefore, the efect of humidity needs to be studied for prolonging the lifetime of organic sensors. In this study, we
propose atomically thin and highly reliable encapsulation layer on the surface of an organic functional material to enhance
its lifetime as a temperature sensing unit. Our organic temperature sensor is based on a conductive and uniform IDT pattern
deposited on a glass substrate through advanced printing technology of reverse ofset. Thin flm of PEDOT:PSS is used as
the temperature sensitive functional layer deposited through electrohydrodynamic atomization while the organic thin flm
was encapsulated with aluminum oxide (Al
2
O
3
) through spatial atmospheric atomic layer deposition system (SAALD). The
temperature range of the developed sensors was from 25 to 90 °C with relative humidity reaching up to 75% RH. The obtained
results exhibited that Al
2
O
3
encapsulation deposited through SAALD signifcantly enhanced the linearity, repeatability,
endurance (50 cycles), retention (1 month) and lifetime of organic temperature sensor as compared to the non-encapsulated
sensor. The performance degradation mechanism of non-encapsulated sensor due to humid environment has been discussed
in detail. This study contributes an important step forward for preserving the performance and elongating the lifetime of
organic electronic devices through a single atomically thin encapsulation.
1 Introduction
Organic polymers have gained signifcant importance in
recent years owing to their promising properties of low cost,
conductivity, fexibility, scalability, light weight, solution
processability, and compatibility with several fabrication
techniques [1–5]. Organic polymers seem to be the ultimate
solution to various medical, industrial and environmental
problems owing to their in-built electrical, mechanical, opti-
cal and chemical characteristics [6]. Numerous electronic
devices have already been reported to date in which organic
polymers act as the functional material for diverse applica-
tions such as OLEDs [7], sensors [8], transistors [9], solar
cells [10], memristors [11–13], batteries [14], and superca-
pacitors [15] etc. However, one major disadvantage restrict-
ing these organic polymer devices from commercialization
at a large scale is degradation in their device performance
due to exposure to ambient environment.
Humidity is the main factor that deteriorates the perfor-
mance of organic devices hence, reducing their lifetime.
Mohammad Mutee ur Rehman and Muhammad Muqeet Rehman
have contributed equally to this work.
Electronic supplementary material The online version of this
article (https://doi.org/10.1007/s10854-018-9572-4) contains
supplementary material, which is available to authorized users.
* Jeong Beom Ko
no1kori@kitech.re.kr
* Kyung Hyun Choi
amm@jejunu.ac.kr
1
Department of Mechatronics Engineering, Jeju National
University, Jeju City, Republic of Korea
2
Faculty of Electrical Engineering, GIK Institute
of Engineering Sciences & Technology, Topi, KPK, Pakistan
3
Department of Electrical Engineering, COMSATS Institute
of Information Technology, Islamabad, Pakistan
4
Department of Engineering, Dankook University, Yongin,
Republic of Korea
5
Korea Institute of Industrial Technology, Gangneung,
Republic of Korea