63
Characterization and Application of Nanomaterials (2021) Volume 4 Issue 1
doi:10.24294/can.v4i1.1291
Original Research Article
Preparation and characterization of magnetic graphene oxide nano-
composite (GO-Fe
3
O
4
) for removal of strontium and cesium from
aqueous solutions
Sule Aytas
1
, Sabriye Yusan
1*
, Senol Sert
1
, Cem Gok
2
1
Institute of Nuclear Sciences, Ege University, 35100 Bornova, Izmir, Turkey. E-mail: sabriye.doyurum@ege.edu.tr
2
Faculty of Technology, Department of Metallurgical and Materials Engineering, Pamukkale University, 20160 Kinikli
Denizli, Turkey
ABSTRACT
Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipi-
tation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the
M-GO was investigated by X-ray difraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectros-
copy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N
2
-
BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I)
ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich
model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.
Keywords: Graphene Oxide; Magnetite; Nanocomposite; Strontium; Cesium, Sorption
ARTICLE INFO
Received: 26 January 2021
Accepted: 12 March 2021
Available online: 18 March 2021
COPYRIGHT
Copyright © 2021 Sule Aytas, et al.
EnPress Publisher LLC. This work is licensed
under the Creative Commons Attribution-
NonCommercial 4.0 International License
(CC BY-NC 4.0).
https://creativecommons.org/licenses/by-
nc/4.0/
1. Introduction
Nuclear and Industrial Safety Agency (Japan) reported that the
Fukushima Daiichi reactor meltdowns have thus far released 15,000
tera becquerels of radioactive cesium-137 into the environment
[1]
. Also,
strontium was measured in plant samples in four others villages, with
values ranging from 12 to 61 Bq/kg for Sr-89 and 1.8 to 5.9 Bq/kg for
Sr-90
[2]
. This accident caused a great environmental disaster for living
metabolisms and plants. Furthermore, diverse anthropogenic activities
like nuclear research reactors, the production and use of radioisotopes
and radiopharmaceuticals bring about the spread of radioactive wastes
in the environment
[3]
.
Some radionuclides as cesium and strontium are biologically toxic
and of great importance due to their long-lasting nature and high solu-
bility in aqueous systems
[4]
. For this reason, it is a signifcant subject to
fnd out efcient, economic method that can be used in the removal and
recovery of cesium and strontium from contaminated environments.
Diferent types of physicochemical methods as ion exchange, chemical
precipitation, membrane separation and adsorption, etc. are used for
removal and recovery of radionuclides. Considering many parameters,
one of these techniques comes to the forefront. Adsorption is wide-
ly-used technique that is fast and efective approach in eliminating pol-
lutants from aqueous solutions
[5]
.