International Journal of Organic Chemistry, 2017, 7, 229-239
http://www.scirp.org/journal/ijoc
ISSN Online: 2161-4695
ISSN Print: 2161-4687
DOI: 10.4236/ijoc.2017.73017 Jul. 27, 2017 229 International Journal of Organic Chemistry
Synthesis, Molecular Structure and
Antibacterial Activity of
1-(4-Methoxybenzaldehyde)-
4-Methylthiosemicarbazone
James Ajeck Mbah
1*
, Godfred Aponglen Ayimele
1
, Norbert Kodjio
2
, Joseph Ngwain Yong
1
,
Emmanuel Ngwang Nfor
1
, Donatien Gatsing
2
1
Department of Chemistry, University of Buea, Buea, Cameroon
2
Department of Biochemistry, Faculty of Science, University of Dschang, Dschang, Cameroon
Abstract
A novel ligand, 1-(4-methoxybenzylidene)-4-methylthiosemicarbazone (MBT)
derived from 4-methoxybenzaldehyde was synthesized and characterized by
spectroscopic methods (IR,
1
H NMR,
13
C NMR), single crystal X-ray diffrac-
tion technique and physical means. MBT showed antibacterial activity in vitro
with MICs of 64 μg/mL (a strain of Salmonella typhi (ATCC 6539)), 128
μg/mL (Salmonella typhi), 64 μg/mL (Salmonella paratyphi A), 128 μg/mL
(Salmonella paratyphi B) and 64 μg/mL (Salmonella typhimurium). The re-
sults showed that MBT demonstrated moderate in vitro antibacterial activity
against a strain of Salmonella typhi (ATCC 6539), Salmonella paratyphi A,
and Salmonella typhimurium, indicating its promise as a possible lead for the
discovery of antibacterial drugs.
Keywords
Novel Schiff Base, Antibacterial Activity, Crystal Structure
1. Introduction
4-Methoxybenzaldehyde (also: p-anisaldehyde, anise aldehyde) is an organic
compound that is commonly encountered in fragrances, both synthetic and nat-
ural [1]. It is a clear liquid with a strong aroma. Anisaldehyde is prepared com-
mercially by oxidation of methoxytoluene (p-cresyl methyl ether) using manga-
nese dioxide. It can also be produced by oxidation of anethole, a related fra-
How to cite this paper: Mbah, J.A., Ay-
imele, G.A., Kodjio, N., Yong, J.N., Nfor,
E.N. and Gatsing, D. (2017) Synthesis, Mo-
lecular Structure and Antibacterial Activity
of 1-(4-Methoxybenzaldehyde)-4-Methyl-
thiosemicarbazone. International Journal of
Organic Chemistry, 7, 229-239.
https://doi.org/10.4236/ijoc.2017.73017
Received: June 16, 2017
Accepted: July 24, 2017
Published: July 27, 2017
Copyright © 2017 by authors and
Scientific Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution International
License (CC BY 4.0).
http://creativecommons.org/licenses/by/4.0/
Open Access