Romanian Biotechnological Letters Vol. 18, No. 6, 2013
Copyright © 2013 University of Bucharest Printed in Romania. All rights reserved
ORIGINAL PAPER
Romanian Biotechnological Letters, Vol. 18, No. 6, 2013 8873
Alcoholic fermentation by yeast immobilized on maize stem disks filled with
Ca-alginate
Received for publication, January 15, 2013
Accepted, October 2, 2013
RADOJKA RAZMOVSKI*, VESNA VUČUROVIĆ
Faculty of Technology, University of Novi Sad, Boulevard Cara Lazara 1, 21000 Novi Sad,
Republic of Serbia,
* corresponding author:Tel.: +38121485376, fax: +38121450413, E-mail address:
razmovski@tf.uns.ac.rs
Abstract
The bioethanol production from sugar beet thick juice using whole cells of Saccharomyces
cerevisiae immobilized by two new combined strategies of yeast natural adhesion onto the maize stem
ground tissue (MSGT) disks and Ca-alginate entrapment was examined in order to improve process
efficiency through use of mechanically resistant and physically stable biocatalyst. The first strategy
involves the development of immobilized biocatalyst in the form of MSGT discs overlaid with Ca-
alginate (IB
1
), while in the second strategy the MSGT discs were filled with Ca-alginate (IB
2
). The IB
1
was physically unstable and inconvenient for repeated batch or continuous processes. In contrast, the
IB
2
showed high mechanical strength, high cells retention and fermentative activity during four
successive cycles without any significant decrease in ethanol production. The average ethanol
concentration, productivity and yield during repeated fermentation of sugar beet thick juice (initial
sugar of 150 g/l) by IB
2
were 69.18 g/l, 1.44 g/lh and 0.473 g/g (92.6% of the theoretical), respectively.
The repeated batch fermentation by IB
2
is useful for reducing the cost of bio-ethanol production due to
the savings in time and energy for inoculum preparation, easier ethanol recovery, and lower need for
the utilization of costly centrifuges for yeast separation.
Keywords: bioethanol; fermentation; Saccharomyces cerevisiae; immobilization; sugar beet
thick juice
Introduction
During the recent years, fermentative production of ethanol from renewable resources has
received attention due to the increasing petroleum shortage [1]. Generally, bioethanol is
produced from sugar-based feedstock (sugar cane, sugar beet, molasses, cane juice, beet
juice), starch-based feedstock (corn, potato, rice, triticale etc.) and cellulosic (bagasse and
wood) resources. In particular, sugar-based feedstock contains readily available fermentable
sugars and can be an ideal substrate for ethanol production by direct fermentation without
need for previous hydrolysis [2]. Owing to the surplus of sugar on the World Market, the
European Union (EU) decided to reduce economic support for refined sugar by about a third,
in order to prevent export of excess sugar to non-EU markets. Because of this, many sugar
producers in Europe are considering to adapt to a combined sugar-ethanol plant in order to
achieve increased profitability and fuel efficiency in the sugar beet processing by using its by-
products for ethanol production [3]. In this context, the overall ethanol production from
different intermediate products (raw juice, thin juice, thick juice) and by-product (molasses)
of the sugar beet processing is very important, especially the assessment of them as the most
suitable substrate for ethanol production. Because of the large amount of fermentable sugars
(approx. 55-65%) accompanied by profuse mineral elements and storability, thick juice was
found to be an excellent feedstock for ethanol production [4].