Pulsed Laser Deposition of Nanostructured Indium-Tin-Oxide Film
Thian Kok Yong
a,b
, Chen Hon Nee
a
, Seong Shan Yap
a,c,*
, Wee Ong Siew
a
, György Sáfran
b
,
Yoke Kin Yap
c
and Teck Yong Tou
a
,
a
Faculty of Engineering, Multimedia University, Cyberjaya, Selangor, Malaysia
a,b
Present Address : Faculty of Engineering and Science, Universiti TAR, Kuala Lumpur, Malaysia
a,c
Present Address : Institute of Physics, Norwegian University of Science and Technology,7491
Trondheim, Norway
b
Research Institute for Technical Physics and Materials Science, Hungarian Academy of Sciences,
Konkoly Thege út 29-33, Budapest XII, Hungary.
c
Department of Physics, Michigan Technological University, 1400 Townsend Drive, Houghton, MI ,
USA, 49931-1295.
ABSTRACT
Effects of O
2
, N
2
, Ar and He on the formation of micro- and nanostructured indium tin oxide (ITO) thin films were
investigated in pulsed Nd:YAG laser deposition on glass substrate. For O
2
and Ar, ITO resistivity of ≤ 4 × 10
-4
Ωcm and
optical transmittance of > 90% were obtained with substrate temperature of 250 °C. For N
2
and He, low ITO resisitivity
could be obtained but with poor optical transmittance. SEM images show nano-structured ITO thin films for all gases,
where dense, larger and highly oriented, microcrystalline structures were obtained for deposition in O
2
and He, as
revealed from the XRD lines. EDX results indicated the inclusion of Ar and N
2
at the expense of reduced tin (Sn)
content. When the ITO films were applied for fabrication of organic light emitting devices (OLED), only those deposited
in Ar and O
2
produced comparable performance to single-layer OLED fabricated on the commercial ITO.
.
Keywords: Indium-tin-oxide (ITO), pulsed laser deposition (PLD), organic light emitting diode (OLED), nanostructures,
nanorod, transparent conducting oxide.
1. INTRODUCTION
Indium tin oxide (ITO) has been used the hole-injection anode [1] in the organic light emitting device (OLED). These are
commonly coated on glass substrate by the magnetron sputtering [2-3], spray pyrolysis [4], electron beam evaporation
[5] and the pulsed laser deposition (PLD) [6-12]. The PLD deposition usually employs either a KrF or ArF excimer laser.
For example, Kim et al. [7-8] reported a low resistivity of 2.0 × 10
-4
Ωcm with a maximum optical transmission of 92%
in the visible region, which was used for the fabrication of OLED. The OLED performance was comparable to that
fabricated using the commercial ITO.
* seong.yap@ntnu.no
Nanostructured Thin Films III, edited by Raúl J. Martin-Palma, Yi-Jun Jen, Akhlesh Lakhtakia, Proc. of SPIE
Vol. 7766, 776615 · © 2010 SPIE · CCC code: 0277-786X/10/$18 · doi: 10.1117/12.869561
Proc. of SPIE Vol. 7766 776615-1
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