Infrared and Raman spectra, ab initio calculations and conformational studies of ethyl iodosilane Valdemaras Aleksa a,b,1 , David L. Powell a,2 , Alytis Gruodis a,1 , Karl Hassler c , Reinhard Hummeltenberg c , Klaus Herzog b , Reiner Salzer b , Peter Klaeboe a, * , Claus J. Nielsen a a Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo, Norway b Institut fu ¨r Analytische Chemie, Technische Universita ¨t Dresden, D-01062 Dresden, Germany c Institut fu ¨r Anorganische Chemie, Technische Universita ¨t Graz, Stremayrgasse 16, A-8010 Graz, Austria Received 5 August 2002; accepted 9 September 2002 Abstract Ethyl iodosilane (CH 3 CH 2 –SiH 2 I) was synthesized for the first time. Infrared spectra were recorded in the vapour, amorphous and crystalline solid phases in MIR and FIR regions. Additional MIR spectra of the compound isolated in argon and nitrogen matrices were obtained at 5 K. Raman spectra of the liquid, excited by argon and by Nd 3þ YAG lasers, were recorded at room temperature including polarization measurements. The spectra were studied in an extended temperature range 173 – 353 K and a DH value of 1.2 ^ 0.3 kJ mol 21 was obtained with gauche being the low energy conformer. Spectra of the amorphous and crystalline solids were obtained at liquid nitrogen temperature. Ethyl iodosilane exists in an equilibrium between anti and gauche conformers, in the vapour, liquid and amorphous states. After careful annealing the amorphous solid on a cold Cu finger (Raman) or on a CsI or Si window (infrared) to 160 K a partly crystalline solid was formed. A number of IR and Raman bands were reduced in intensity after annealing, although they did not vanish completely. From comparison between the observed and calculated vibrational modes it was apparent that the gauche conformer was present in the crystal. The sample was mixed with argon and nitrogen in a ratio 1:1000, deposited on a window at 5 or 10 K and annealed to temperatures between 5 and 36 K (argon) and 5 – 30 K (nitrogen). IR bands attributed to the anti and gauche conformers were reduced and increased in intensities, respectively. Thus, the gauche conformer was the low energy conformer in the matrices and probably also in the vapour phase. Ab initio calculations were performed at the RHF/3-21 G* and 6-311G* B3LYPs and gave optimized geometries, IR and Raman intensities and vibrational frequencies for the anti and gauche conformers. An enthalpy difference of 0.9 kJ mol 21 was obtained from the calculations with gauche being the low energy conformer. After scaling, a reasonably good agreement between the experimental and calculated wavenumbers for the anti and gauche conformer was obtained. The spectra of ethyl iodosilane were closely related to those of the corresponding ethyl fluoro, ethyl chloro and ethyl bromosilane. q 2002 Elsevier Science B.V. All rights reserved. Keywords: Infrared spectra; Ethyl iodosilane; Raman spectra; Matrix isolation spectroscopy; Conformations; Ab initio calculations 0022-2860/03/$ - see front matter q 2002 Elsevier Science B.V. All rights reserved. PII: S0022-2860(02)00480-5 Journal of Molecular Structure 644 (2003) 105–118 www.elsevier.com/locate/molstruc 1 Permanent address: Department of General Physics and Spectroscopy, Vilnius University, Vilnius 2734, Lithuania. 2 Permanent address: Department of Chemistry, The College of Wooster, Wooster, OH 44691, USA. * Corresponding author. Tel.: þ 47-2285-5678; fax: þ 47-2285-5441. E-mail address: peter.klaboe@kjemi.uio.no (P. Klaeboe).