Hindawi Publishing Corporation
Physics Research International
Volume 2011, Article ID 186704, 6 pages
doi:10.1155/2011/186704
Research Article
Isobaric Study of the Elastic Properties for
Alkaline Earth Oxides under High Temperature
Seema Gupta,
1, 2
S. P. Singh,
2
and S. C. Goyal
1, 2, 3
1
Department of Physics, Agra College, Agra 282002, India
2
Department of Physics, Goverment Degree College, Sambhal, Moradabad, India
3
K. P. Engineering College, N. H. 2, Etmadpur, Agra 283202, India
Correspondence should be addressed to Seema Gupta, seema g khushi@yahoo.co.in
Received 20 September 2010; Revised 7 March 2011; Accepted 9 March 2011
Academic Editor: Fahrettin Yakuphanoglu
Copyright © 2011 Seema Gupta et al. This is an open access article distributed under the Creative Commons Attribution License,
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
A simple and straightforward theoretical model is developed to investigate the elastic properties of alkaline earth oxides under the
effect of temperature as well as pressure. The calculation is performed with the help of high pressure-high temperature equation
of state based on thermodynamic analysis. The anharmonic term arising due to thermal expansion has been taken into account in
the expansion of logarithmic series of the thermodynamic data. The results obtained for alkaline earth oxides are discussed and
compared with experimental data under the combined effect of high temperature and high pressure. The results are found to be
in good agreement with available experimental results.
1. Introduction
The equation of state (EOS) gives us valuable information
about the change in bulk under the influence of temperature
at a fixed pressure and is thus related to the compression
of solids. The study of elasticity plays an important role
in describing the high-temperature behaviour of solids.
The studies based on the equation of state (EOS) are vide
importance in physics as well as in chemistry and in the
earth sciences [1, 2]. The theoretical studies of EOS at
high temperature and pressure are of fundamental interest
because they permit interpolation and extrapolation into the
regions in which the experimental data are spares or lacking.
It is the necessary to know the effects of the temperature
and pressure on the elastic properties of alkaline earth
oxides (AEOs) throughout the upper mantle of the Earth
for better understanding about its structure, compositions,
and mineralogy. The properties of alkaline earth oxides
solids under varying conditions of temperature and pressure
have attracted the attention of theoretical and experimental
workers [3–9] because of their need in different branches of
science [10].
The problem of evaluation of elastic moduli can be
tackled in two different ways, for example, (i) by deter-
mining the constants or elastic moduli from temperature
relationship, termed as equation of state [3–7] and (ii) by
choosing suitable interionic potential and there by evaluating
elastic constants and elastic moduli [11–13]. Both methods
help us to determine various properties of solids under
varying conditions of pressure and temperature. It has been
observed that the methods based on the theory of interionic
potentials are very tedious [11–16] and involve a lot of
computational work in addition to various approximation
and it fails to evaluate the elastic constants or elastic moduli
of complicated solids.
The purpose of the present study is to present a
simple and straightforward method for evaluation of elastic
constants of simple and complex solids at different tem-
peratures. To determine the temperature dependence of
elastic constants and their combination, different relations
based on thermodynamic parameters have been proposed
in the literature [17]. The well-known and widely used
relations for predicting the temperature dependence of
elastic constants are discussed by Suzuki et al. [18] and by