Scientific Research Journal (SCIRJ), Volume VII, Issue XII, December 2019 25
ISSN 2201-2796
www.scirj.org
© 2019, Scientific Research Journal
http://dx.doi.org/10.31364/SCIRJ/v7.i12.2019.P1219734
Synthesis, Characterization and Biological Activities of
2, 5-Dimethyl-4-Methoxy[5,6-b]Benzo[2,3-a]Pyrolo-4-
Keto Thiazine-1,1-Dioxide
Bodunde Joseph OWOLABI
1
, David Iregbeyaogene IRAOYA
1
, Taiwo Sholagbade ADEPOJU
1
*
1
Chemistry Department, Federal University of Technology, Akure, Nigeria.
*: Corresponding Author's email address: tsadepoju@futa.edu.ng
DOI: 10.31364/SCIRJ/v7.i12.2019.P1219734
http://dx.doi.org/10.31364/SCIRJ/v7.i12.2019.P1219734
ABSTRACT: Microbial infections remain harrowing menace to health sector globally with distressing effects such as prolonged
hospitalization, morbidity and high cost for treatment. The research was conducted to develop effective therapeutic agents against
pathogens. Firstly, 2, 5-Dimethyl-4-sulphonyl proline anisole was synthesized from reaction between 2, 5-dimethyl-4-
methoxybenzene sulphonyl chloride and L-proline in basic medium. Thereafter, 2, 5-dimethyl-4-methoxy[5,6-b]benzo[2,3-a]pyrolo-
4-keto thiazine-1,1-dioxide was synthesized from the intermediate using thionyl chloride and triethyl amine. The synthesized
compounds were characterized by FTIR and NMR. Then, antimicrobial activities of the compounds were studied. Both compounds
inhibited the growth of tested bacteria and fungi. 2, 5-dimethyl-4-methoxy[5,6-b]benzo[2,3-a]pyrolo-4-keto thiazine-1,1-dioxide gave
better antibacterial activities, even than commercial drug while 2, 5-Dimethyl-4-sulphonyl proline anisole exhibited stronger
antifungal activities.
Keywords: Pathogens, therapeutics, infections, antimicrobials and 2, 5-dimethyl-4-methoxy[5,6-b]benzo[2,3-a]pyrolo-4-keto
thiazine-1,1-dioxide
1.0 INTRODUCTION
Microbial infections remain harrowing menace to health sector globally with distressing effects such as prolonged hospitalization,
morbidity and high cost for treatment [1, 2]. Additionally, the capacity of pathogenic microorganisms to resist therapeutic activities of
drugs has reduced the effectiveness of these drugs, making the development of new drugs a matter of necessity. Sadly speaking, the
pace at which new drug is being introduced to the market is extremely low compared to the tempo at which pathogens develop
resistance [3]. Thus, the development of effective antimicrobials stands as pressing need worldwide.