The inuence of drained peat soils on diffuse nitrogen pollution of surface water Anatoli Vassiljev and Irina Blinova ABSTRACT Eutrophication caused by excess nutrient loads is the main problem for Estonian surface waters. Even after the drastic decrease in the application of mineral fertilizers at the beginning of the 1990s, the concentrations of nitrogen and phosphorus in many rivers remained at undesirable and unexpectedly high levels. The investigation showed that drained peat soils are an important source of nitrogen export to the surface waters. Runoff of nitrogen from drained peat soils is, on average, 1.5-fold higher than from agricultural lands in Estonia. Anatoli Vassiljev (corresponding author) Tallinn University of Technology, Ehitajate tee 5, Tallinn 19086, Estonia E-mail: avasil@staff.ttu.ee Irina Blinova National Institute of Chemical Physics and Biophysics, Akadeemia tee 23, Tallinn 12618, Estonia Key words | diffuse pollution, nutrients, peat soils, river water quality INTRODUCTION According to the Water Framework Directive (), good status of surface water must be achieved by the year 2015. However, the eutrophication, caused by enlarged loads of nutrients (nitrogen and phosphorus) from watersheds, still remains one of the most important problems for surface waters in Estonia (Iital et al. ). In many rivers, the con- centrations of nutrients exceed the upper hydrochemical limit values of good status established in Estonia (3 mg/L for total nitrogen and 0.08 mg/L for total phosphorus (Classes )). Nitrogen concentrations in some rivers exceed the limit ve-fold. It is sometimes impossible to explain such high nitrogen concentrations by known pol- lution sources. This fact impedes elaboration of the effective water protection measures. According to current opinion, the drastic increase of sur- face water pollution by nutrients during the late 1970s was caused, above all, by efuent discharge (point sources) and by intensive use of commercial fertilizer in agriculture (dif- fuse pollution). As a result, primary attention has been focused on the measures for reducing the nutrient loads from the above-mentioned sources. Reconstruction of old sewage treatment plants and opening new ones has signi- cantly decreased nutrient pollution load from point sources during the last decades. However, it has been esti- mated that in Estonia diffuse sources play a noticeable role in the formation of the total nutrient load. For example, 60% of the total annual nitrogen load and 40% of the total phosphorus load from the Lake Peipsi watershed (nearly one-third of the territory of Estonia) come from diffuse sources (Vassiljev & Stålnacke ). The changes in the agricultural sector of Estonian economy at the beginning of the 1990s led to a drastic decrease in the application of mineral fertilizers (Figure 1) and also in livestock popu- lation. Nevertheless, very little evidence that these changes in agricultural practices noticeably affected the concen- trations of nutrients in rivers was found (Blinova & Vassiljev ; Stålnacke et al. ; Lepistö et al. ). The nutrients runoff from some watersheds remained at undesirable and unexpectedly high levels. This fact conrms the opinion that the impact of agriculture (particularly use of mineral fertilizers) on the pollution of surface water by nutrients was overestimated (Thomas et al. ). Hoffmann et al.() hypothesized that intensive pol- lution of surface water by nutrients in Sweden and Finland in the 1960s was caused not only by agricultural activity but also by wide-scale melioration, which was conducted at the same time. The signicant increase of nutrient runoff from drained areas was also observed after the drai- nage of forests and peatlands (Lundin & Bergquist ; Prévost et al. ). Peat soils can act as a source as well 352 © IWA Publishing 2012 Hydrology Research | 43.4 | 2012 doi: 10.2166/nh.2012.117 Downloaded from http://iwaponline.com/hr/article-pdf/43/4/352/371077/352.pdf by guest on 16 January 2024