Global Journal of Engineering and Technology Advances, 2019, 01(01), 022–026
Global Journal of Engineering and Technology Advances
Cross Ref DOI: 10.30574/gjeta
Journal homepage: http://www.gjeta.com
Corresponding author
E-mail address: smithonyekwere@gmail.com
Copyright © 2019 Author(s) retain the copyright of this article. This article is published under the terms of the Creative Commons Attribution Liscense 4.0.
(R ESEARCH A RTICLE )
Determination of percentage zinc loss during melting of zinc scrap in a crucible
furnace
Onyekwere, Okwuchi Smith
1, *
Orji, Chiawolamoke Ihenwokeleme
2
and Uyanga, Kindness Alfred
3
1
Faculty of Engineering, Federal University Wukari Taraba State, Nigeria.
2
Department of Welding and Fabrication, Abia State Polytechnic Aba, Nigeria.
3
School of Energy and Environment, City University of Hong Kong, Kowloon, Hong Kong.
Publication history: Received on 15 October 2019; revised on 02 December 2019; accepted on 04 December 2019
Article DOI: https://doi.org/10.30574/gjeta.2019.1.1.0004
Abstract
During the melting process of zinc scraps, not all the zinc metals in the scrap are recovered. This article evaluates the
extent of zinc loss during melting of zinc scraps. Zinc scraps were melted in a charcoal-fired crucible furnace, and the
percentage zinc loss was determined. Two modes of zinc loss were observed – zinc loss through evaporation and zinc
loss through the dross. It was determined that 2.2 percentage of the total zinc was lost through evaporation while 10.8
percentage of the total weight was lost in the dross when zinc scrap was melted without fluxing. The total zinc loss when
zinc scrap was melted without fluxing was found to be 13 percent. With fluxing, using chloride-salt based flux (17%
KCl, 20% NaCl, 63% ZnCl2 salt system), 0.79weight percent and 1.74weight percent was lost through evaporation and
dross respectively. The total zinc loss was reduced to 2.53weight percent with fluxing. This work will help foundrymen
in method and economic decision making when working on zinc scraps.
Keywords: Zinc Loss; Zinc Alloys; Dross; Zinc recovery; Zinc scrap
1. Introduction
Zinc alloys have been used in the production of various parts such as car carburettors, door handles, etc. Based on
historical consumption, it is estimated that currently, 30-40% of the cast zinc components used in manufacture are
being recovered and recycled [1].Recycling zinc alloys from scraps has energy savings advantage over processing zinc
composites. The ability to melt zinc scrap many times without losing its properties is of significant benefit to the zinc
die caster. However, it is important to keep the material clean and free of unwanted substances [2].
Despite cleaning of the scraps, oxide films and some unwanted substances are also found in the zinc melt. When an alloy
melt reacts with the atmosphere or moisture, it forms an amorphous continuous oxide film on the surface of the bath.
These oxide films are an essential part of the melting process because they protect the metal underneath from further
oxidation. Also, during the melting of the scraps, some have inserts that may not be very economical to remove before
the melting operation. Some of the inserts made of iron and aluminium will dissolve in the zinc melt up to their
respective solubility limits. Dissolution above their solubility limit will cause the formation of intermetallic compounds,
in particular, the zinc-iron and zinc-iron-aluminium compounds with high proportions of entrained zinc [3]. In the
process of removing these unwanted substances, zinc will be lost.
Zinc dross is a mixture of metallic materials contained in a matrix of zinc. During melting of zinc scrap, the intermetallic
compounds formed will adversely affect the wetting characteristics of the zinc slag, causing the dross to encapsulate
free zinc metal; thus the resultant dross is rich in metallic zinc which cannot easily be mechanically separated. Skimming
out the dross will mean substantial loss in the zinc metal. In foundry operations, the surface of the molten bath is always
moving due to charging, skimming, cleaning, transferring, ladling, etc. Any of these melting practices causes the thin film