S1 Cleavage of sp 3 C−O Bonds via Oxidative Addition of C−H Bonds Jongwook Choi, Yuriy Choliy, Xiawei Zhang, Thomas J. Emge, Karsten Krogh-Jespersen,* Alan S. Goldman* Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903 E-mail: alan.goldman@rutgers.edu ; krogh@rutchem.rutgers.edu Supporting Information Part II: Crystal Structure Data Page # X-Ray Structure Determination S3 I. Structural Data for 3a (a) Figure S-1. ORTEP Diagram of 3a S4 (b) Table S1. Crystal data and structure refinement for 3a S5 (c) Table S2. Atomic coordinates for 3a S6 (d) Table S3. Bond lengths and angles for 3a S8 (e) Table S4. Anisotropic displacement parameters for 3a S12 (f) Table S5. Hydrogen coordinates for 3a S14 (g) Table S6. Torsion angles [°] for 3a S16 II. Structural Data for 4b (a) Figure S-2. ORTEP Diagram of 4b S18 (b) Table S7. Crystal data and structure refinement for 4b S19 (c) Table S8. Atomic coordinates for 4b S20 (d) Table S9. Bond lengths and angles for 4b S23 (e) Table S10. Anisotropic displacement parameters for 4b S32 (f) Table S11. Hydrogen coordinates for 4b S35 (g) Table S12. Torsion angles [°] for 4b S38 III. Structural Data for 4c (a) Figure S-3. ORTEP Diagram of 4c S42 (b) Table S13. Crystal data and structure refinement for 4c S43