178 Int. J. Global Warming, Vol. 10, Nos. 1/2/3, 2016
Copyright © 2016 Inderscience Enterprises Ltd.
Sulphur removal from Artvin-Yusufeli lignite with
acidic hydrogen peroxide solutions
Menderes Levent*
Department of Chemical Engineering,
Uşak University,
Uşak, 64100, Turkey
Email: menderes.levent@usak.edu.tr
*Corresponding author
Ömer Kaya
SASA Polyester Company,
Adana, Turkey
Email: omer.kaya@sasa.com.tr
M. Muhtar Kocakerim
Department of Chemical Engineering,
Çankırı Karatekin University,
Çankırı, Turkey
Email: mkocakerim@yahoo.com
Özkan Küçük
Department of Material Sci. and Nanotech. Eng.,
Kastamonu University,
Kastamonu, Turkey
Email: okucuk@kastamonu.edu.tr
Abstract: In this study, the optimisation of sulphur removal by H
2
O
2
/H
2
SO
4
solutions, and a limited kinetic measurements by H
2
O
2
/HCl solutions have been
carried over Artvin/Yusufeli lignite. In kinetic measurements, only the effect of
temperature on removal of sulphur has been investigated. By keeping all other
parameters constant, with increments in temperature at different times, it has
been seen that removal of sulphur is increased. A statistical experimental
arrangement which has six parameters and for each parameter there is twenty
five experiments with five levels. In generally, pyritic sulphur, total sulphur,
organic sulphur and ash removal rates have been determined. According
to carried out variance analysis, in removal of pyritic and total sulphur,
all parameters are effective, but, in removal of organic sulphur, acid
concentration and particle size are not effective, and in removal of ash, only,
acid concentration is not effective, however, all other parameters are effective.
Keywords: desulphurisation; pyritic sulphur; total sulphur; organic sulphur;
lignite; hydrogen peroxide.