ORIENTAL JOURNAL OF CHEMISTRY
www.orientjchem.org
An International Open Access, Peer Reviewed Research Journal
ISSN: 0970-020 X
CODEN: OJCHEG
2019, Vol. 35, No.(6):
Pg. 1805-1812
This is an Open Access article licensed under a Creative Commons license: Attribution 4.0 International (CC- BY).
Published by Oriental Scientific Publishing Company © 2018
Development of Stability Indicating, Validated Liquid
Chromatographic Method for Estimation of Sarecycline
in its Formulations
AZMATH UNISSA
1
, ANUPAMA KONERU
2
, M.MUSHRAFF ALI KHAN
3
,
MURALI BALARAM VARANASI
1
and IMAM PASHA SYED
1
*
1,2,3
Department of Pharmaceutical Quality Assurance, Sultan-ul-Uloom College of Pharmacy, Mount
Pleasant, #8-2-249, Road No. 3, Banjara Hills, Hyderabad-500034, Telangana, India.
*Corresponding author E-mail: impazam@gmail.com, imampharmaceuticalsciences@gmail.com
http://dx.doi.org/10.13005/ojc/350625
(Received: November 28, 2019; Accepted: December 29, 2019)
ABSTRACT
A stability indicating HPLC method was developed and for the estimation of Sarecycline
Hydrochloride in tablet dosage form using C
18
column with a mobile phase composition of
0.1M Na
2
PO
4
and Acetonitrile in the ratio of 50:50 v/v . The detection wave maxima and retention time
were found to 242nm and 3.876 min respectively. The method validation was carried out according to
International Council for Harmonization of Technical Requirements for Pharmaceuticals for Human
Use (ICH) guidelines and the parameters namely; precision, accuracy, specificity, stability, robustness,
linearity, limit of quantitation (LOQ) and limit of detection (LOD) are evaluated. The present developed
RP-HPLC method shows the purity angle of peaks is less than their threshold angle, signifying that
it to be suitable for stability studies. Hence, the developed method can be used for the successful
estimation of Sarecycline in the pharmaceutical dosage formulations.
Keywords: Sarecycline Hydrochloride, RP-HPLC, Formulation, Validation.
INTRODUCTION
The drug used in the present study is
Sarecycline hydrochloride, chemically (4S,4a
S,5aR,12aR)-4-(Dimethylamino)-1,10,11,12
a-tetrahydroxy-7-[[methoxy(methyl)amino]methyl]-
3,12-dioxo-4a,5,5a,6-tetrahydro-4H-tetracene-2-
carboxamide and the structure was shown in Fig.1.
It inhibits protein synthesis and other biosynthetic
activities and shows anti-inflammatory action
1
.
Sarecycline is a semi-synthetic derivative of
tetracycline that was initially discovered by Paratek
Pharmaceuticals from Boston, MA but then licensed
to Warner Chilcott of Rockaway, NJ . After completing
various phase-II and phase-III trials demonstrating
its effectiveness in treating moderate to severe facial
acne vulgaris the US Food and Drug Administration
approved Barcelona based Almirall, S.A.'s Seysara
(sarecylcine) as a new first in class narrow spectrum
tetracycline derived oral antibiotic for the treatment