Available online at www.sciencedirect.com
ScienceDirect
Materials Today: Proceedings 5 (2018) 3361–3368
www.materialstoday.com/proceedings
2214-7853© 2017 Elsevier Ltd. All rights reserved.
Selection and/or Peer-review under responsibility of 7th International Conference of Materials Processing and Characterization.
ICMPC 2017
Growth and characterization of
L-histidinium perchlorate crystals (LHP)
S. Nalini Jayanthi
a
* , N. Bhuvaneswari
a
a
Department of Physics, KCG College of Technology, Chennai, India
Abstract
L-histidinium perchlorate, a semi-organic nonlinear optical (NLO) material was synthesized by standard slow evaporation
solution growth technique. The single crystals were subjected to various characterizations. Powder XRD and FT-IR spectral
analysis were carried out confirm the LHP crystals. The nonlinear optical behavior of the crystal was tested using Kurtz-Perry
powder technique. The suitability of the crystal in device fabrication was confirmed by testing its thermal stability. The
photoconducting property of the crystal was also studied.
© 2017 Elsevier Ltd. All rights reserved.
Selection and/or Peer-review under responsibility of 7th International Conference of Materials Processing and Characterization.
Keywords:Solutiongrowth, Semiorganic, NLO, Thermal properties
1. Introduction
The search and design of highly efficient nonlinear optical (NLO) crystals for visible and ultraviolet (UV)
regions are extremely important for laser and material processing. Semi-organic NLO crystals formed with
L-histidine has been identified as potential candidates for replacing KDP in nonlinear optical applications because
they have the combined advantages of both organic and inorganic materials [1]. Amino acids and inorganic acids are
good raw material to produce semi-organic crystals [2,3].
In the present investigation, a systematic study has been carried out on the growth of L-histidinium perchlorate
(LHP) crystals by slow solvent evaporation technique. The grown crystals were subjected to powder XRD to
* Corresponding author. Tel.: +91-988-499-2842
E-mail address:nalinijayanthi80@hotmail.com