S1
Structure and Reactivities of Rhenium and Technetium bis‐arene Sandwich
Complexes [M(
6
‐arene)
2
]
+
Giuseppe Meola, Henrik Braband, Sara Jordi, Thomas Fox, Oliver Blaque, Bernhard Spingler and
Roger Alberto
Department of Chemistry, University of Zurich, Winterthurerstr. 190, CH‐8057 Zurich Switzerland.
Supplementary Information
Table of Content
1. General Information
1.1 Materials
1.2 Characterization
2. Synthetic procedures
2.1 [
99
Tc(
6
‐hmbz)(
6
‐C
6
H
5
‐NH
3
)](PF
6
)
2
([1‐H](PF
6
)
2
) and [
99
Tc(
6
‐pmbz)(
6
‐C
6
H
5
‐NH
3
)](PF
6
)
2
([2‐H](PF
6
)
2
)
2.2 [
99
Tc(
6
‐hmbz)
2
](PF
6
) ([3a](PF
6
)) and [
99
Tc(
6
‐pmbz)(
6
‐hmbz)](PF
6
) ([3b](PF
6
))
2.3 [
99
Tc(
6
‐hmbz)(
6
‐C
6
H
5
‐Br)](PF
6
) ([4](PF
6
)) and [
99
Tc(
6
‐pmbz)(
6
‐C
6
H
5
‐Br)](PF
6
) ([5](PF
6
))
2.4 [
99
Tc(
6
‐hmbz)( (
6
‐C
6
H
6
)](PF
6
) and [
99
Tc(
6
‐pmbz)( (
6
‐C
6
H
6
)](PF
6
)
2.5 [Re(
6
‐C
6
H
6
)(
6
‐napht)](OTF) ([6](OTf))
2.6 [Re(
6
‐napht)
2
](OTf) ([7](OTf))
2.7 [Re(
6
‐C
6
H
6
)(tep)
3
](OTf) ([8](OTf))
2.8 [Re(
6
‐C
6
H
6
)(CN‐
t
Bu)
3
](OTf) ([9](OTf))
2.9 [Re(
6
‐C
6
H
6
)(HB(pyz)
3
)] (10)
2.10 [Re(η
6
‐napht)(tep)
3
](PF
6
) ([11](PF
6
))
2.11 [Re(η
6
‐napht)(triphos)](PF
6
) ([12](PF
6
))
2.12 [Re(CN‐
t
Bu)
6
](PF
6
) ([13](PF
6
))
Electronic Supplementary Material (ESI) for Dalton Transactions.
This journal is © The Royal Society of Chemistry 2017