The concept of compressing soft materials to very
high pressures between two opposed anvils was
developed a century ago by Bridgman at Harvard
University. But it was not until 1959 that diamonds
were used as the anvil material, even though
diamond’s unique properties, such as extreme
hardness and transparency to light and X-rays, had
been known for a long time. The first diamond anvil
apparatus was constructed at the National Bureau of
Standards in Washington, DC by Weir and Van
Valkenburg
1
and by Jamieson and colleagues at the
University of Chicago
2
. It was developed further by
Peter Bell and Ho-Kwang Mao at the Carnegie
Institution and Arthur Ruoff at Cornell University.
Even in these early studies, pressures of several
hundred thousand atmospheres could be generated at
room temperature, and it was immediately clear that
under such high pressures fundamental changes in the
physical behavior of materials were to be expected.
At that time, nobody dreamed of converting a noble gas
like Xe into a metal at a pressure just above a megabar
3,4
.
Then, about 30 years ago, Bassett and coworkers
5
introduced
laser heating to the diamond cell and opened an even larger
field of research, including the study of phase behavior,
chemical reactions, material synthesis, and mineral and metal
properties under conditions found in planetary interiors.
A general objection to using diamond anvils as a synthesis
tool is the extremely small yield. However, one should keep
in mind that, when diamonds were first synthesized at high
by Reinhard Boehler
Diamond cells
and new materials
Max-Planck-Institut für Chemie,
P.O. Box 3060,
55020 Mainz,
Germany
E-mail: boe@mpch-mainz.mpg.de
November 2005 34
ISSN:1369 7021 © Elsevier Ltd 2005
The diamond anvil apparatus, invented nearly
50 years ago, has developed into a versatile tool for a
broad spectrum of high-pressure research topics,
ranging from low-temperature physics to
high-temperature geoscience. It is superbly suited for
high-pressure and high-temperature synthesis
because new materials can be identified and
characterized in situ. The combination of high
pressure and high temperature, generated by two
opposed diamond anvils and infrared (IR) lasers,
respectively, has allowed the simulation of the
extreme conditions of planetary interiors, the
discovery of new structures and behavior in elements,
and the synthesis of novel hard materials. Here, we
describe the relatively simple technique of generating
and controlling high pressure and high temperature,
and present recent examples related to these topics.