238
U–
230
Th disequilibrium in recent basalts and dynamic melting
beneath the Kenya rift
N.W. Rogers
a,
⁎
, L.E. Thomas
a
, R. Macdonald
b
, C.J. Hawkesworth
c
, F. Mokadem
a
a
Department of Earth Sciences, CEPSAR, The Open University, Milton Keynes, MK7 6AA, UK
b
Environment Centre, Lancaster University, Lancaster, LA1 4YQ, UK
c
Department of Earth Sciences, The University of Bristol, Wills Memorial Building, Queens Rd., Bristol, BS8 1RJ, UK
Received 7 October 2005; received in revised form 27 April 2006; accepted 2 May 2006
Abstract
Trace element and U-series isotope analyses are presented for a suite of recent (<10 ka) basalts from the axial portion of the
Kenya rift. Samples from throughout the rift have LREE-enriched patterns with HREE > 10 × chondrite and the LREE between 60
and 200 × chondrite. REE fractionation is consistent with melting a garnet lherzolite source region with between 2% and 6% modal
garnet. Other trace element ratios are distinct from OIB, notably Zr/Hf which ranges from 43 to 48, whilst at a given Zr content the
Zr/Hf ratio is significantly greater than that found in OIB. (
238
U/
232
Th) range from 0.362 to 1.036, (
230
Th/
232
Th) from 0.503 to
1.109, with (
230
Th/
238
U) ranging from 0.783 to 2.966. All but two samples are in
230
Th excess or in secular equilibrium. Samples
with elevated (
238
U/
232
Th), also have Rb/Cs > 120, but unexceptional
208
Pb
⁎
/
206
Pb
⁎
and hence κ
Pb
values. These samples have
experienced U and Cs loss and are excluded from further consideration. Of the unaltered samples, all have (
238
U/
232
Th) generally
lower than OIB, with maximum values of < 0.8, and some < 0.6. The maximum (
230
Th/
238
U) is 1.39, similar to OIB. Although none
of the basalts has a primary composition, (
230
Th/
238
U) does not vary systematically with indices of fractionation, and comparison
with evolved rocks from Kenya indicates that
238
U–
230
Th disequilibrium in the basalts is not the product of fractionation and
crustal residence, but a product of melt generation. The maximum (
230
Th/
238
U) that can be generated by batch melting, assuming a
source mineralogy consistent with the REE variation is 1.05 and so the variation in (
230
Th/
238
U) is attributed to more complex
models of melt generation and/or transport. Both dynamic melting and equilibrium porous flow suggest mantle upwelling rates of
≤ 2 cm year
- 1
. It is suggested that the Kenya basalts represent melts derived from lithospheric mantle that has been thermally
reactivated by and incorporated into the underlying (East African) mantle plume.
© 2006 Elsevier B.V. All rights reserved.
Keywords: U-series; Trace elements; Basalts; Kenya rift; Melt generation
1. Introduction
Continental basaltic magmatism reveals a composi-
tional diversity that is somewhat greater than that
observed in the oceanic realm. While in part this relates
to the interaction of mafic magmas with the more easily
fusible parts of the continental crust, much composi-
tional diversity has been attributed to magma sources
located in the continental mantle lithosphere—that part
of the mantle attached to the base of the continents,
forming part of the plate structure that does not take
part in mantle convection. Petrological investigations
Chemical Geology 234 (2006) 148 – 168
www.elsevier.com/locate/chemgeo
⁎
Corresponding author. Tel.: +44 1908 652013; fax: +44 1908
655151.
E-mail address: n.w.rogers@open.ac.uk (N.W. Rogers).
0009-2541/$ - see front matter © 2006 Elsevier B.V. All rights reserved.
doi:10.1016/j.chemgeo.2006.05.002