Food Hydrocolloids vol.l no.l pp.89-93, 1986
SHORT COMMUNICATION
Comparative studies of the mechanical properties of mixed
gels formed by kappa carrageenan and tara gum or carob
gum
P.Cairns, V.J.Morris, M.J.Miles and G.J.Brownsey
AFRC Food Research Institute (Norwich), Colney Lane, Norwich NR4 7UA, UK
Abstract. Tara gum has been considered as a possible replacement for carob gum in the formation of kappa
carrageenan - galactomannan mixed gels. The mechanical properties of tara - carrageenan mixed gels have
been measured and compared with the mechanical properties of carob-carrageenan mixed gels.
Introduction
Polysaccharides are important gelling agents used by the processed food industry.
Synergistic interactions between food-approved polysaccharides are attractive commer-
cially and may be exploited technologically. Such mixtures may be used to replace ex-
pensive polysaccharides by cheaper alternatives leading to savings in cost, and they
offer the possibility for creating new textures or for manipulating the rheology and tex-
ture of foods.
The mixtures kappa carrageenan - carob and xanthan - carob have been successfully
exploited by the food industry. This article is concerned with possible replacements
for the kappa carrageenan -carob system. The galactomannan carob gum is extracted
from the seeds of Ceratonia siliqua, a tree which may only be cultivated in a few areas
of the world. Climatic changes could restrict the supply of carob gum, leading to an
increase in price. There is a need to continually develop new polysaccharides or polysac-
charide mixtures as alternatives in applications which at present use carob gum. There
are several short-term solutions to the reduced supply and increased cost of carob gum.
Firstly, the kappa carrageenan -carob gum mixture could be replaced by a new polysac-
charide. Microbial polysaccharides grown by fermentation offer the prospect of a con-
trolled and stable cost and supply. Gellan gum has been developed as a broad spectrum
gelling agent (1) and it has been demonstrated (1) that it may be used to replace the
kappa carrageenan -carob gum mixtures in typical food applications. However, gellan
gum has not, as yet, been cleared for food use. Should such approval be granted, then
the cost of gellan gum will ultimately determine whether it is adopted as a replacement
for kappa carrageenan -carob gum by the food industry. Secondly, other galactomannans
could be modified to replace carob gum. It has been demonstrated (2) that the rheological
properties of the galactomannan and kappa carrageenan mixture depend on the
galactose - mannose ratio of the galactomannan. Enzymatic removal of galactose from
guar gum yields a modified guar gum which forms mixed gels with kappa carrageenan
(3). However, enzyme-modified guar gum would also require testing before clearance
could be given for food use. Thirdly, other galactomannans may have sufficiently low
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