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Materials Today: Proceedings 13 (2019) 876–881 www.materialstoday.com/proceedings
2214-7853 © 2019 Elsevier Ltd. All rights reserved.
Peer-review under responsibility of the scientific committee of the International Conference on Materials and Environmental Science, ICMES
2018.
ICMES 2018
Setting Properties of Calcium Phosphate Bone Cement
M. Fathi
a*
, A. Kholtei
b
, S. EL Youbi
a
, B. Chafik El Idrissi
c
*
a
Laboratoire, Ingénierie des Matériaux et Environnement : Modélisation et Application Faculté des Sciences Ibn Tofail , Kenitra, Maroc.
b
Laboratory of Chemistry Biology Applied to Environment, Mouly Ismail University, Faculty of Science, BP11201 Meknes, Morocco
c
Team Materials Surfaces Interfaces, Laboratory Materials and Energitics, Fac of Sciences, University Ibn Tofail, Kenitra, Morocco
Abstract
Calcium phosphate cements (CPCs) are widely used in bone repair. CPCs show many advantages comparing to other calcium
phosphate-based materials because of its chemical similarity to the mineral constituent of natural bone. This work describes a
new apatitic calcium phosphate cement composition with a Ca/P ratio = 1.38, by mixing two components which were prepared
by wet chemical synthesis methods. One component is chemically synthesized by mixing α-tricalcium phosphate (αTCP,
Ca
3
(PO
4
)
2
) and HA (Ca
10
(PO
4
)
6
OH)
2
), while the second component is again a chemically synthesized single phase DCPD
(CaHPO
4
.2H
2
O) powder. The sitting solution used is 3 wt% Na
2
HPO
4
. 2H
2
O dissolved in distilled water with a liquid to powder
ratio L/P = 0.4. The cement was characterized in terms of setting time, compressive strength. XRD and SEM techniques were
employed to evaluate the phase composition and surface morphology of the cement, the powder XRD data shows that the cement
sample soaked in water has transformed into calcium deficient hydroxyapatite. The cement showed a fast setting time (14 min),
this cement also showed a high compressive strength (35 MPa).
© 2019 Elsevier Ltd. All rights reserved.
Peer-review under responsibility of the scientific committee of the International Conference on Materials and Environmental
Science, ICMES 2018.
Keywords: Calcium phosphate cement; Calcium deficient hydroxyapatite; Setting time; Compressive Strength ;
1. Introduction
Calcium phosphate cements (CPCs) are biocompatible materials that possess a self-hardening feature, also
referred to as self-setting bones cements, and have been used in medical and dental applications for many years.
CPC shows many advantages compared to other calcium phosphate‐based. Due to the high level of interest and
* Corresponding author. Tel.: +212610018138.
E-mail address: fathimajda@hotmail.com