Review
Phosphorous recovery through struvite crystallization: Challenges for
future design
Bing Li
a,b
, Irina Boiarkina
a
, Wei Yu
a,
⁎, Hai Ming Huang
c
, Tajammal Munir
a
,
Guang Qian Wang
b
, Brent R. Young
a
a
Department of Chemical & Materials Engineering, The University of Auckland, New Zealand
b
Department of Hydraulic Engineering, Tsinghua University, China
c
School of Environmental and Chemical Engineering, Yanshan University, China
HIGHLIGHTS
• A trend analysis of current research on
struvite crystallization was performed.
• All factors affecting struvite crystalliza-
tion were reviewed.
• Current gaps and future research direc-
tions were identified.
• A conceptual struvite crystallization
process design was proposed.
GRAPHICAL ABSTRACT
abstract article info
Article history:
Received 29 May 2018
Received in revised form 13 July 2018
Accepted 13 July 2018
Available online 05 August 2018
Editor: Frederic Coulon
Phosphorous (P) is an essential element for living organisms and is predicted to be depleted within the next
100 years. Across the world, significant phosphorous losses due to its low utilization efficiency become one of
the main reasons for water pollution. Struvite crystallization has been found to be a promising recovery technique
to mitigate these problems, as the recovered precipitate can be used as a slow release fertilizer or raw material for
chemical industry. Although this technique has been widely investigated over the past two decades, there are cur-
rently few real applications in industry. This paper addresses this issue by reviewing key aspects relevant to pro-
cess design to pave the way for future application. It will help to narrow down struvite process design options and
thus reduce the voluminous calculations for a detailed analysis. Struvite process development, research trend,
product application and process economics are reviewed and a conceptual process design is provided. This analysis
provides comprehensive information that is essential for future industrial struvite crystallization process design.
© 2018 Elsevier B.V. All rights reserved.
Keywords:
Struvite
Phosphorus recovery
Process design
Product application
Product quality
Contents
1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1245
2. An overview of research activity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1245
Science of the Total Environment 648 (2019) 1244–1256
⁎ Corresponding author.
E-mail address: w.yu@auckland.ac.nz (W. Yu).
https://doi.org/10.1016/j.scitotenv.2018.07.166
0048-9697/© 2018 Elsevier B.V. All rights reserved.
Contents lists available at ScienceDirect
Science of the Total Environment
journal homepage: www.elsevier.com/locate/scitotenv