Asfew et al. Functional Composite Materials (2022) 3:8
https://doi.org/10.1186/s42252-022-00036-6
RESEARCH
Temperature dependence of thermophysical
properties of carbon/polyamide410 composite
Kasahun Niguse Asfew
1,2*
, Jan Ivens
1
and David Moens
3
Abstract
In this study, the temperature dependence of the carbon/polyamide 410 composite’s heat capacity, thermal expan-
sion, density, and thermal conductivity was investigated. The results demonstrated that the specific heat capacity of
the C/PA410 composite increases with temperature, with major transitions observed at the glass transition (Tg) and
melting (Tm) temperatures. Due to the presence of fibers, the CTE values in the fiber direction of C/PA410 specimens
were one order of magnitude smaller than in the transverse direction. The density measurements reveal that as
temperature rises, volume increases, causing density to decrease. The heat diffusivity of the C/PA410 composite was
measured using the laser flash technique, which was then used to calculate thermal conductivity. The results show
that the average thermal conductivity in the fiber direction increases linearly with temperature, while in the transverse
direction it increases linearly with temperature up to 50 °C and then becomes constant between 50 °C and 100 °C.
Keywords: Temperature dependence, Carbon/polyamide composites, Specific heat capacity, Coefficient of thermal
expansion, Thermal conductivity
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Introduction
In the production of thermoplastic composite products,
the material must be processed at high temperatures,
which afects its thermophysical properties. Accurate
thermal simulations require knowledge of temperature-
dependent thermophysical properties. Consequently,
it is becoming increasingly important to investigate the
behavior of thermoplastic composites at elevated tem-
peratures. Te efect of temperature on thermal difu-
sivity, thermal conductivity, heat capacity, coefcient
of thermal expansion (CTE), and density of isotropic or
anisotropic materials has been the subject of research by
several scientists. Te studies [1–4] used the laser fash
method, transient plane source (TPS) [5], and modulated
DSC [6] to determine the thermal difusivity, derived
heat capacity, and thermal conductivity of isotropic met-
als and fber-reinforced polymer composites (FRPC).
Te efects of the fnite width of the laser fash pulse,
heat loss, and specimen thickness in thermal difusiv-
ity measurement [7] and the infuence of the stacking
sequence of composite specimens and frequency of the
source on thermal wave distribution [8] in the laser fash
method have been studied. In the laser fash method, a
program was used to analyze and calculate thermal dif-
fusivity values from images acquired using an IR camera
[9]. Te temperature dependence of specifc heat capac-
ity, thermal difusivity, and thermal conductivity of dif-
ferent composite materials has been studied by several
researchers [3]. Te thermal conductivity of semi-crys-
talline and four amorphous polymers was determined
starting at room temperature and [10] going up to tem-
peratures above the polymer melting point (Tm) for
semi-crystalline polymers or above the glass transition
temperature (Tg) for amorphous polymers, and the peak
thermal conductivity values are observed around Tg for
amorphous and around Tm for semi-crystalline poly-
mers. [11] presented a three-dimensional thermal difu-
sivity method using lock-in thermography for isotropic
and anisotropic materials.
Open Access
Functional Composite
Materials
*Correspondence: Kasahunniguse.asfew@kuleuven.be
1
Department of Materials Engineering, KU Leuven Campus De Nayer, J. De
Nayerlaan 5, 2860 Sint-Katelijne-Waver, Belgium
Full list of author information is available at the end of the article