C80 Mineral Processing and Extractive Metallurgy (Trans. Inst. Min. Metall. C) June 2005 Vol. 114
INTRODUCTION
The production of various grades of potassium
feldspar from pegmatitic ores has been carried out
over the years world-wide.
1
It is well known that the
product quality and its value depend on K
2
O and
colouring mineral contents, namely iron and titanium
oxides. Usually, the K
2
O content is improved by
separating quartz by employing flotation and/or
magnetic separation depending on ore characteristics.
Dry magnetic separation by rare-earth permanent
magnets is nowadays the cheapest and most widely
used method of separating the colouring minerals.
2,3
However, it is not efficient for separation of minerals
with very low magnetic susceptibilities like quartz and
albite. Luckily, flotation is well suited and allows the
separation of all minerals, including orthoclase–albite
separation, to increase the K
2
O content of concentrates
further.
4
However, only feldspar–quartz flotation
technology has been commercially explored and the
floatation of orthoclase selectively from albite largely
ignored. There are some studies in the literature showing
that this can be achieved by using raw table salt (NaCl) as
a depressant for sodium feldspar.
5
Hence, it was decided to
study if a low-grade pegmatitic ore could be a source of
high-grade potassium feldspar.
EXPERIMENTAL
Materials
The samples used in the experimental studies were
received from different low-grade pegmatitic ore veins
in Demirci Province in the west of Turkey. Thin-
section studies indicated that the matrix consisted of
feldspar and quartz bearing brownish to black
disseminated bands of impurities; orthoclase, albite,
quartz and mica minerals were generally coarse
grained, ranging between 0·5–20 mm; the grain size of
titanite and rutile was relatively fine being 0·02–0·6
mm and they were mostly found in feldspar minerals
as inclusions. With regard to adequate liberation
fineness, the ore had to be –300 µm.
DOI 10.1179/037195505X39085
Production of potassium feldspar concentrate from a low-grade
pegmatitic ore in Turkey
Ö. Y. Gülsoy, N. M. Can and I. Bayraktar
This paper describes the possibility of producing various
grade feldspar concentrates by magnetic separation and
flotation. A representative sample was obtained from the
Manisa–Demirci region. It was composed of 5·94% K
2
O,
3·14% Na
2
O, 0·61% CaO, 0·41% MgO, 0·11% TiO
2
,
0·65% Fe
2
O
3
, 15·7% Al
2
O
3
and 73·08% SiO
2
as deter-
mined by the XRF technique. Microscopic studies on thin
sections revealed that muscovite, biotite, tourmaline,
sphene and rutile were disseminated in various sizes
ranging between 20–500 µm in the matrix of orthoclase,
albite and quartz, and for an adequate liberation the
sample had to be ground to –300 µm. The non-magnetics
were a basic mixture of feldspars and quartz with an
alkaline content of 5·86% K
2
O and 2·96% Na
2
O, which
was raised to 13·44% (9·22% K
2
O + 4·22% Na
2
O) by
only feldspar flotation. For further improvement of
K
2
O, orthoclase was differentially floated while albite
was simultaneously depressed with NaCl. Finally, a
high-grade potassium feldspar concentrate was
produced composed of 12·65% K
2
O, 3·1% Na
2
O, 0·11%
Fe
2
O
3
, and 0·04% TiO
2
with a glossy white firing button
at 1200°C.
Ö. Y. Gülsoy (for correspondence – E-mail: ogulsoy@
hacettepe.edu.tr) and N. M. Can (E-mail: metin.can@
hacettepe.edu.tr) are in the Mining Engineering Department,
Hacettepe University, Beytepe Ankara, Turkey; and I.
Bayraktar is at Çine Akmaden Madencilik Tic. A.S., Aydin-
Karpuzlu Karayolu 33. km, 09500 Çine/Aydin, Turkey (E-
mail: cineakmaden@cineakmaden.com.tr).
© 2005 Institute of Materials, Minerals and Mining and
Australasian Institute of Mining and Metallurgy. Published
by Maney on behalf of the Institutes. Manuscript received 23
October 2004; accepted in final form 4 March 2005.
Keywords: Feldspar concentrate, magnetic separation,
flotation, pegmatitic ore
Table 1 The feed assay and the source of compounds of the
samples
Compounds Assay (%) Main source
SiO
2
73·08 Quartz and feldspars
Al
2
O
3
15·70 Feldspar, micas
Fe
2
O
3
0·54 Tourmaline, biotite, some stains of iron
oxides
TiO
2
0·09 Titanite, rutile, biotite and muscovite
MgO 0·41 Biotite
CaO 0·61 Plagioclase
K
2
O 5·94 Orthoclase, micas
Na
2
O 3·14 Albite, tourmaline
LOI 0·49