Research Article
Removal of Heavy Metal Ions (Pb
2+
,Co
2+
, and Cd
2+
) by Activated
Carbon from Cypress Fruit: An Investigation of Kinetics,
Thermodynamics, and Isotherms
Alaa M. Al-Ma’abreh , Dareen A. Hmedat , Gada Edris , and Mariam A. Hamed
Department of Chemistry, Faculty of Science, Isra University, P.O. Box 22, Amman 11622, Jordan
Correspondence should be addressed to Alaa M. Al-Ma’abreh; alaa.almaabreh@iu.edu.jo
Received 30 October 2023; Revised 5 April 2024; Accepted 10 April 2024; Published 25 April 2024
Academic Editor: Liviu Mitu
Copyright © 2024 Alaa M. Al-Ma’abreh et al. Tis is an open access article distributed under the Creative Commons Attribution
License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly
cited.
In this study, activated carbon cloth (ACC) derived from cypress fruit was employed to investigate the adsorption of Pb
2+
, Cd
2+
,
and Co
2+
from synthetic aqueous systems. Te correlation between adsorption features (pH, adsorbent dosage, temperature,
initial ion concentration, and contact time) and adsorbent removal efciency was investigated. Analysis by FT-IR, SEM, and EDS
was employed to confrm the adsorption of metal ions onto the ACC. Results revealed the best adsorption efciencies for heavy
metal ions were attained at pH = 7, 11, 6; the adsorbent dosage of 0.06, 0.08, and 0.04 g for Pb
2+
,Cd
2+
, and Co
2+
, respectively; the
ion initial concentration of 50 mg·L
−1
for Pb
2+
and 70 mg·L
−1
for both Co
2+
and Cd
2+
; and contact time of 90 minutes for both
Pb
2+
and Co
2+
and 120 minutes for Cd
2+
. Kinetic studies exposed the second-order adsorption of all aforementioned heavy metal
ions. Additionally, the equilibrium data were ftted by Langmuir and Freundlich’s isotherms, while the former performed better
than the latter. Te maximum adsorption capacity values for Pb
2+
,Co
2+
,andCd
2+
were attained to 81.87, 55.30, and 117.3mg·g
−1
,
respectively. Considering the thermodynamic data, the studied processes were exothermic and spontaneous.
1. Introduction
Water pollution is a global environmental challenge that
continues to pose signifcant threats to the well-being ofboth
ecosystems and human populations. As one of the most vital
resources on our planet, water serves as a lifeline for all living
organisms, sustaining biodiversity, agriculture, industry,
and domestic needs [1]. However, human activities, in-
dustrialization, agricultural practices, and improper waste
disposal have led to the contamination of water bodies with
various pollutants. Tese contaminants include a broad
variety of materials that end up in rivers, lakes, seas, and
groundwater sources, such as heavy metals, hazardous
compounds, fertilizers, and microplastics [2]. Te efects of
water pollution are extensive, leading to the deterioration of
aquatic environments, a decline in biodiversity, and the
threat to many species. Furthermore, drinking tainted water
puts one’s health in danger for both acute and chronic
illnesses. Since the level of water pollution is still rising,
strong scientifc research, environmentally friendly man-
agement techniques, and cooperative eforts at the local,
national, and international levels are all needed to address
this situation [3]. An urgent environmental worry nowadays
is heavy metal pollution, which is brought on by the dis-
charge of hazardous elements like lead (Pb), cobalt (Co),
chromium (Cr), mercury (Hg), and cadmium (Cd) into the
environment. Because they are the result of several an-
thropogenic activities, these heavy metals are extremely
dangerous to natural systems and human health. It is well
known that hazardous elements may bioaccumulate in or-
ganisms and be persistent in the environment. Tis can have
detrimental consequences on human organs, such as the
kidneys, liver, and nervous system. Furthermore, the im-
balance of an ecosystem is upset by heavy metal contami-
nation, which hurts plant growth, soil fertility, and aquatic
life. Providing efcient mitigation solutions requires an
Hindawi
Journal of Chemistry
Volume 2024, Article ID 1984821, 13 pages
https://doi.org/10.1155/2024/1984821