Journal of Sol-Gel Science and Technology https://doi.org/10.1007/s10971-019-05092-2 ORIGINAL PAPER: NANO- AND MACROPOROUS MATERIALS (AEROGELS, XEROGELS, CRYOGELS, ETC.) Thermal decomposition of manganese carbonyl in supercritical CO 2 as a simple and effective approach to obtain manganese oxide aerogels Vadim V. Zefirov 1,2 ● Igor V. Elmanovich 1,2 ● Alexander V. Pastukhov 2 ● Elena P. Kharitonova 1 ● Alexander A. Korlyukov 2 ● Marat O. Gallyamov 1,2 Received: 8 May 2019 / Accepted: 22 July 2019 © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract A novel approach to synthesize metal oxide aerogels is presented. The monolith aerogel structure is formed using dimanganese decacarbonyl as a precursor at elevated temperatures directly in supercritical CO 2 . Unlike previously described and developed sol–gel approaches, the proposed synthetic route requires only several hours without any necessity either to add any additional reaction-promoting liquid agents or to perform prolonged gel aging, solvent exchange, or supercritical drying steps. The morphology of the obtained aerogels was studied by means of scanning and transmission electron microscopy. Using low-temperature nitrogen adsorption technique, it was demonstrated, that achievable surface area of the aerogels could be tailored by varying the precursor concentration. Eventually, aerogels with a specific surface area of up to 170 m 2 /g were obtained. Graphical Abstract * Vadim V. Zefirov vv.zefirov@physics.msu.ru 1 Faculty of Physics, Lomonosov Moscow State University, Leninskie gory 1-2, 119991 Moscow, Russian Federation 2 A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russian Federation Supplementary information The online version of this article (https:// doi.org/10.1007/s10971-019-05092-2) contains supplementary material, which is available to authorized users. 1234567890();,: 1234567890();,: