Thermodynamic Casimir Force in Models of 4 He Films Based on vortex-loop renormalization group techniques (VLRGT), Williams [1] has predicted the finite-size scal- ing functions (SF) describing the excess free energy (EFE) and the (thermodynamic) Casimir force (CF) for the three- dimensional XY model in a film geometry with thickness L and under periodic boundary conditions (PBC). These pre- dictions concern the region close to and below the critical temperature T b c of the bulk system. Within this approach the Casimir amplitude (CA), characterizing the film at T b c , is given as XY 0:155 while the "-expansion (EE) result [2] is XY 0:20. Rescaling the high temperature results from the EE [2] with the ratio of the above ampli- tudes, Williams has constructed a SF for the force in the whole critical region by patching together the EE curve with the low temperature VLRGT results, which renders a rather smooth matching at T b c [1]. In Fig. 1 we compare this approach with recent Monte Carlo (MC) data for the same system [3]. The data for the VLRGT approach shown in Fig. 1 are obtained from a numerical solution of the equa- tions given in Ref. [1] by the same method. An inspection of Fig. 1 and of Fig. 2 in Ref. [1] shows that the MC data are at variance both qualitatively and quantitatively with VLRGT for T & T b c where one expects for ON 2mod- els to see the pronounced effect of the Goldstone modes (GM). This is born out by the MC results, but is completely missing within the VLRGT approach. Furthermore, if, using the Williams approach, one matches the MC and the VLRGT data at T T c , a new (artificial) cusplike singularity will be created in the SF of the CF. Because of the contribution due to the GM, the CF (and the EFE) SF tends to a negative constant. The VLRGT approach, in its present form [1], does not account for this effect. Note that there is no theoretical proof available that the decomposi- tion of the CF into a sum of a noncritical ‘‘Goldstone part’’ and a ‘‘critical part’’ to be covered by VLRGT (Fig. 1) gives a good approximation to the total force. Experimental data (ED) for 4 He films [4] require a theoretical description based on Dirichlet boundary con- ditions (DBC). Above T b c the EE results [2] available for this case are in good agreement with the ED. Because of inherent difficulties in that case there are, however, neither analytical nor MC results available for the critical region below T b c . Very recently, for DBC and T well below T b c the asymptotic regime of large L has been analyzed in Ref. [5]. These calculations take into account the capillary wavelike surface fluctuations that occur on one of the bounding surfaces of the actual 4 He wetting film studied in Ref. [4]. One finds a suppression of the SF for x ! 1 which is comparable with the ED. Whereas there are significant discrepancies between the MC data and the VLRGT approach for PBC, there is agreement between the actual ED [4] described by DBC and corresponding theoretical descriptions within their range of applicability, i.e., for T T b c [2] and T T b c [5]. It remains as a challenge to confirm and to understand the deep minimum (ca. 50 times deeper than the value at T b c ) of the experimental SF for temperatures slightly below T b c . For this temperature range for DBC there are presently no theoretical predictions available. D. Dantchev, 1,2,3 M. Krech, 2,3 and S. Dietrich 2,3 1 Institute of Mechanics Bulgarian Academy of Sciences Academic G. Bontchev Street 4 1113 Sofia, Bulgaria 2 Max-Planck-Institut fu¨r Metallforschung Heisenbergstrasse 1 D-70569 Stuttgart, Germany 3 Institut fu¨r Theoretische und Angewandte Physik Universita¨t Stuttgart D-70569 Stuttgart, Germany Received 18 June 2004; published 14 December 2005 DOI: 10.1103/PhysRevLett.95.259701 PACS numbers: 74.78.w, 64.60.Fr, 75.40.s [1] G.A. Williams, Phys. Rev. Lett. 92, 197003 (2004). [2] M. Krech and S. Dietrich, Phys. Rev. A 46, 1886 (1992); 46, 1922 (1992). [3] D. Dantchev and M. Krech, Phys. Rev. E 69, 046119 (2004). [4] R. Garcia and M. H. W. Chan, Phys. Rev. Lett. 83, 1187 (1999). [5] R. Zandi, J. Rudnick, and M. Kardar, Phys. Rev. Lett. 93, 155302 (2004). [6] M. Krech, Phys. Rev. E 56, 1642 (1997). -0.40 -0.35 -0.30 -0.25 -0.20 -0.15 -0.10 -0.05 0 -10 -7.5 -5.0 -2.5 0 2.5 5.0 7.5 10 x = L / MC,L = 12 MC,L = 16 MC,L = 20 MC,L = 24 vortex loop [1] - expansion [2] spherical model [4] ξ θ (x) / 2 per ε FIG. 1 (color). Scaling function per x L==2 of the CF for the d 3XY model in a slab obtained from MC [3] and EE [2] for PBC. Here T T b c  is the bulk correlation length with t T T b c =T b c & 0  0 jtj , 0:67. In order to be able to make contact with Ref. [1], as a measure of the temperature below T b c we define T T b c  jtj. The vertical scale of the MC data has been adjusted such that there is agreement with the estimate per 0 2 XY 0:56 [3] which is obtained by using EE results for the ratio Ising = XY of the CA of the Ising and the XY model, and the best known numerical value of Ising ’0:153 [6]. Note that both the (properly normalized) [3] EE and the MC results practically coincide with the (exact) spherical model results for x * 2, which for PBC renders the limit N !1 of the ONmodels. PRL 95, 259701 (2005) PHYSICAL REVIEW LETTERS week ending 16 DECEMBER 2005 0031-9007= 05=95(25)=259701(1)$23.00 259701-1 © 2005 The American Physical Society