Evidence for a high T c magnetic amorphous polymorph obtained by swift heavy ion irradiation M. Ghidini a, * , J.P. Nozieres b , F. Bolzoni c , G. Suran b , J.F. Gregg a , B. Gervais d a Clarendon Laboratory, University of Oxford, Parks Road, OXI 3PU, Oxford, UK b Laboratoire L. N eel, Avenue des Martyrs, BP 166 X, 38042, Grenoble Cedex, France c Istituto MASPEC del CNR, via Chiavari 18/A, 43100 Parma, Italy d CIRIL, BP 5133, 14040 Caen Cedex, France Abstract The intermetallic compound CeCo 3 has been irradiated at GANIL by 1 GeV 208 Pb ion beams. The irradiated samples are found to be strongly amorphised. A track diameter of 8 nm is found. The magnetic properties of the ir- radiation induced CeCo 3 amorphous phase have been studied in detail and found substantially dierent with respect to those of amorphous CeCo 3 obtained by conventional methods. In particular, an increase of about 200 K in the Curie temperature is observed, suggesting that a dierent type of chemical short range order might have been stabilized by irradiation. Ó 1998 Elsevier Science B.V. All rights reserved. PACS: 75.70.Cn; 73.23.b Keywords: Latent tracks; Amorphous magnetism; Thermal spike 1. Introduction Amorphous metals and alloys can be obtained by rapid cooling either from the liquid or the vapour phase by dierent techniques [1,2]. It is well-known that amorphous samples produced by dierent methods can show dierent properties. This is generally ascribed to dierent degrees of structural relaxation, resulting from dierent amounts of strain frozen in the samples during the rapid cooling process. However, such dierences are normally quite small [3,4]. In a few cases, for a given composition, substantial dierences in the magnetic properties have been observed in alloys prepared with strongly dierent quenching rates [3,5]. Detailed studies have shown that this was due to two dierent types of Chemical Short Range Order (CSRO) (amorphous polymorphism) [6]. CeCo 3 is a metallic ferromagnet [7]. As 3d- magnetism of cobalt is normally more robust in the amorphous state than in the crystalline state [3], a spontaneous magnetic moment of about 0:2 l B =f :u: and a Curie temperature T c of 80 K are reported for crystalline CeCo 3 [8], while a Nuclear Instruments and Methods in Physics Research B 146 (1998) 260±264 * Corresponding author. Address: Dip.to di Fisica, Univer- sita' di Parma, v.le delle Scienze, 43100 Parma Italy. Tel.: +39 521 90521; fax: +39 521 905223; e-mail: Ghidini@®s.unipr.it 0168-583X/98/$ ± see front matter Ó 1998 Elsevier Science B.V. All rights reserved. PII: S 0 1 6 8 - 5 8 3 X ( 9 8 ) 0 0 4 9 1 - 1