Reverse osmosis membrane modified by
interfacial polymerization in non-polar heptane
solvent assistance with acetone as a co-solvent
A. S. Al-Hobaib, M. S. Alsuhybani & Kh. M. Al-Sheetan
Nuclear Science Research Institute,
King Abdulaziz City for Science and Technology (KACST), Saudi Arabia
Abstract
The present work is focused on developing a suitable chemical membrane with
polyamide, incorporating co-solvents. There are many benefits of using a
membrane technique. It is cost-effective and can be fabricated easily and its
materials have less effect on the environment. Therefore, the general membrane
techniques have been used for the desalination of ocean water as a worldwide
strategy to meet the demand for clean water. But in some cases the use of this
membrane becomes limited when pore size, distribution of pores and low
selectivity for pollutants/contaminants are considered. The fabrication of such a
membrane with co-solvents is expected to lead to a solution to address some of
these problems. In this study, a polyamide thin-film composite membrane was
developed by interfacial polymerization in non-polar heptane solvent, using
acetone as a co-solvent medium. The modified membranes were characterized by
different techniques. Scanning electron microscope and atomic force microscopy
images showed a smooth membrane surface. Thermo-gravimetric analysis
indicated that these developed membranes possessed high thermal stability. High
contact angles were observed in the presence of acetone as a co-solvent in the
polyamide membrane. Similarly, high fluxes were observed with low salt rejection
ability.
Keywords: interfacial polymerization, RO membrane modified, co-solvent.
Water Resources Management VIII 245
www.witpress.com, ISSN 1743-3541 (on-line)
WIT Transactions on Ecology and The Environment, Vol 196, © 2015 WIT Press
doi:10.2495/WRM150211