Jurnal Akademika Kimia, 12(1): 44-51, February 2023
ISSN (online) 2477-5185 | ISSN (print) 2302-6030
http://jurnal.fkip.untad.ac.id/index.php/jak/ OPEN ACCESS
44
1
Activation of Durian Skin Biomass with H2SO4 Activator on the
Absorption of Lead from its Solution
Fahrul Riski, Irwan Said, Afadil, & Purnama Ningsih
Program Studi Pendidikan Kimia/FKIP – Universitas Tadulako, Palu – Indonesia 94119
Received 28 October 2022, Revised 23 January 2023, Accepted 15 February 2023
doi: 10.22487/j24775185.2023.v12.i1.pp44-51
Abstract
Research has been carried out on the bioabsorption of lead (Pb) using durian skin biomass (Durio zibethinus) which
has been activated using an H2SO4 activator. The durian skin sample used was durian skin from Central Sulawesi. The
processing technique to remove lead (Pb) from liquid waste was carried out by an adsorption process. The adsorption process
is an effective purification and separation technique used in industry because it is more economical and simple in treating
wastewater and is a technique that is often used to reduce metal ions in wastewater. This study aims to determine the mass
and contact time of the adsorption of Pb by durian skin biomass. Determination of the adsorbed metal used atomic
absorption spectrophotometry (AAS). The results obtained showed that the optimal Pb ion adsorption occurred at a weight
of 2.5 grams with an absorption capacity of 99.94%. While the optimal Pb ion adsorption occurred at a contact time of 40
minutes with an absorption capacity of 99.94%.
Keywords: Durian skin, activation, adsorption, biomass, Pb metal
Introduction
Water is one of the most abundant natural
resources on earth and the main component of life
processes. Water that can be used must meet
physical, chemical, and microbiological
requirements (Athena et al., 2004; Burlakoti et al.,
2020).
The increasing human activity in the
industrialization era hurts human life and the
surrounding environment. The widespread use of
heavy metals in the form of salts for industrial
purposes is one of the main factors for increasing
heavy metal pollution in water bodies (Briffa et al.,
2020).
One type of heavy metal that causes water
pollution is lead (Pb). Lead (Pb) is easily purified so
it is widely used by humans in various activities.
Environmental pollution by lead (Pb) mostly comes
from human activities that extract and exploit the
metal. The Pb content in water can cause health
problems such as intestinal disorders, unpleasant
odors, causing a yellow color on the walls of the
bathroom tub, and yellow spots on clothes
(Darmono, 2001; Al-Tohamy et al., 2022).
Several methods or processing techniques to
remove Pb from water have been carried out by
physical and chemical processes (Soria-Aguilar et al.,
2021). One of the methods that can be used is the
*Correspondence:
Fahrul Riski
e-mail: fahrulriski9999@gmail.com
© 2023 the Author(s) retain the copyright of this article. This article is published under the terms of the Creative Commons
Attribution-NonCommercial-ShareAlike 4.0 International, which permits unrestricted non-commercial use, distribution, and
reproduction in any medium, provided the original work is properly cited.
adsorption method. The adsorption process is an
effective purification and separation technique used
in industry because it is considered more
economical in water and wastewater treatment and
is a technique that is often used to reduce metal ions
in wastewater (Selvi et al., 2001; Algarni & Al-
Mohaimeed, 2022).
The use of adsorption techniques requires an
adsorbent. Treatment costs are an important
parameter in selecting adsorbents and the cost of
each adsorbent varies greatly, depending on the
process required and the availability of the
adsorbent. One of the materials used is durian skin,
which is proportionally high in cellulose (50 – 60
%), lignin (5 %), and low starch content (5 %)
(Masturi et al., 2018). This cellulose can be used as
a metal binder (Apriani et al., 2013). Based on these
contents, durian peel can be used as a potential raw
material in the manufacture of adsorbents (Noer et
al., 2015). In terms of structure, durian consists of
three parts, namely the flesh about 20 – 30 %, the
seeds about 5 – 15 %, and the skin about 60 – 75
% (Jaguaribe et al., 2005; Herlina et al., 2016). To
improve the quality of the adsorbent, an activation
process can be carried out. Where the activation
process aims to enlarge the pores by breaking
hydrocarbon bonds or oxidizing surface molecules
so that the adsorbent changes properties, both
physical and chemical, namely the surface area