Environ Monit Assess (2012) 184:527–538
DOI 10.1007/s10661-011-1985-y
Atmospheric background trace elements deposition
in Tierra del Fuego region (Patagonia, Argentina),
using transplanted Usnea barbata lichens
Marcelo Enrique Conti · Maria Grazia Finoia ·
Beatrice Bocca · Giustino Mele ·
Alessandro Alimonti · Anna Pino
Received: 9 September 2010 / Accepted: 23 February 2011 / Published online: 16 March 2011
© Springer Science+Business Media B.V. 2011
Abstract Lichen, Usnea barbata, transplants taken
from Tierra del Fuego (south Patagonia, Argentina)
were tested as potential biomonitors of at-
mospheric airborne deposition in an apparently
pristine environment. In 2005, lichens were sam-
pled in a reference site (n = 31) and transplanted
in the northern Region of Tierra del Fuego. After,
respectively, 1 month and 1 year of exposure,
we collected them. The aim of the study was to
determine the bioaccumulation of 26 elements in
order to evaluate the background levels in the se-
lected area. Samples were analyzed by the sector
field inductively coupled plasma mass spectrome-
M. E. Conti (B) · G. Mele
Department of Management and Technologies,
Sapienza University of Rome, Via del Castro
Laurenziano 9, 00161 Rome, Italy
e-mail: marcelo.conti@uniroma1.it
M. E. Conti
International Academy of Environmental Sciences
(IAES), Campo della Chiesa, 3 Sant’Elena,
30122 Venice, Italy
M. G. Finoia
Istituto Superiore per la Protezione e la Ricerca
Ambientale (ISPRA), Via di Casalotti 300,
00166 Rome, Italy
B. Bocca · A. Alimonti · A. Pino
Istituto Superiore di Sanità,
Viale Regina Elena, Rome, Italy
try. Discriminant analysis on principal component
analysis factors was applied in order to explore the
relationship among the different elements as far as
time and spatial variation in transplants regards.
The analysis was tested by Monte Carlo test based
on 999 replicates. The most important contami-
nation source resulted to be the atmospheric soil
particle deposition. Furthermore, the results were
compared with those obtained from the lichens
collected in central and southern Tierra del Fuego.
This study confirms the ability of U. barbata to
reflect the background levels of the 26 elements
in that environment. Compared with other back-
ground sites in the world, we did confirm that
Tierra del Fuego lichens have a low content of the
studied elements. Tierra del Fuego turned out not
to be a pristine environment as supposed, but it
can be considered as a reference basal ecosystem
for useful comparisons among different geograph-
ical areas. These findings can be very relevant and
useful for environmental conservation programs.
Keywords Lichen transplants · Trace elements ·
Usnea barbata · Multivariate analysis ·
Tierra del Fuego
Introduction
Over the last decades, biomonitoring methods
have been widely used. Direct analysis of abiotic