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Current Biochemical Engineering, 2020, 6, 000-000 1
RESEARCH ARTICLE
2212-7119/20 $65.00+.00 © 2020 Bentham Science Publishers
Effect of Choline Acetate on the Yeast Cells During Fermentation: Kinetics
Approach
Amal A. Elgharbawy
1,*
, Md. Zahangir. Alam
2
, Muhammad Moniruzzaman
3
, Nassereldeen Ahmad Kabbashi
2
,
Parveen Jamal
2
and Shiva Rezaei Motlagh
4
1
International Institute for Halal Research and Training (INHART), International Islamic University Malaysia, PO Box
10, Kuala Lumpur 50728, Malaysia;
2
Department of Biotechnology Engineering, Kulliyyah of Engineering, Internation-
al Islamic University Malaysia, PO Box 10, Kuala Lumpur 50728, Malaysia;
3
Chemical Engineering Department, Cen-
tre of Research in Ionic Liquids (CORIL), Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Malaysia;
4
Department of Chemical and Environmental Engineering, Faculty of Engineering, University Putra Malaysia, 43400
UPM, Serdang, Selangor, Malaysia
Abstract: Background: Ionic liquids (ILs) are claimed as green solvents and have demonstrated abil-
ity in the dissolution of several biomaterials and polymers, thus promoting their applications in wide
scope. The aim of this study was to evaluate the yeast cells in the ionic liquid (IL), choline acetate
[Cho]OAc as an eco-friendlier IL for their growth and ability of fermentation of the empty fruit bunch
(EFB) biomass for ethanol production via monitoring the cell growth curve and kinetics.
Methods: The Saccharomyces cerevisiae was cultured for five days on yeast extract-peptone-dextrose
(YPD) agar and the sub-culturing was carried out every two weeks to evaluate the growth of yeast in
[Cho]OAc at different concentrations; 5%, 10%, and 20%, where it was pre-cultivated for 24 h at
30 °C and 150 rpm in a shaking incubator as a control culture. Yeast cell number was determined by
counting using a hemocytometer. Also, the kinetic growth of yeast during the fermentation of EFB
was evaluated.
Result: cell concentration increased, ethanol production increased along with the optical density with
the peak reached at 72 h, then declined. Enzymatic hydrolysis process followed by fermentation of
EFB using [Cho][OAc] improved the yield of sugar, saccharification and ethanol around 1.938, 2.879,
and 2.165 times in comparison with untreated EFB with IL. Furthermore, values of specific growth
rates obtained in IL-medium and non-IL-medium are applicable for ethanol production to take place.
The results showed the ability of yeast cells for fermentation even in the presence of IL.
Conclusion: The results showed that the presence of the IL did not suppress the growth of the yeast
cells and did not impair the fermentation productivity.
A R T I C L E H I S T O R Y
Received: April 16, 2020
Revised: July 01, 2020
Accepted: July 22, 2020
DOI:
10.2174/2212711906999200816125102
Keywords: Ionic liquids, fermentation, hydrolysis, cellulase, kinetics, growth curve.
1. INTRODUCTION
Ionic liquids (ILs), which are regarded as “green sol-
vents,” have attractive properties, including their ability to
dissolve complex carbohydrates and other biomaterials and
polymers. ILs are salts in a liquid state and typically have
melting points below 100 °C. As such, these compounds
possess characteristics that make them attractive for a broad
range of applications. While costly to purchase or produce in
the laboratory, their overall performance and prolonged re-
use-ability allow for the costs associated with the initial
*Address correspondence to this author at the International Institute for
Halal Research and Training (INHART), International Islamic University
Malaysia, PO Box 10, Kuala Lumpur 50728, Malaysia; Tel: 0162464208;
E-mails: amalgh@iium.edu.my; amal.elgharbawy@gmail.com
capital expenditure to be offset over time [1]. Some ILs have
been used in many applications as clean solvents as green
process catalysts, as well as in photochemistry and electro-
synthesis. Because of the adaptable properties of ILs, en-
zymes exhibit enhanced activity or stability in the presence
of some ILs [2] An IL containing an appropriate combination
of the cationic and anionic parts might considerably increase
substrate specificity, improve the selectivity, or enhance the
bioprocess in concern [3, 4]. To date, presenting ILs into
many industrial processes has enhanced productivity, yield,
and provides an additional benefit of reuse and recyclability
[5, 6]. The expanding popularity of ILs and the recent pro-
duction on a large scale due to their possible applications
could lead to their release uncontrollably into the environ-
ment. Therefore, more safety details and concerns should be
addressed in order to presume the green and clean prospect