ORIENTAL JOURNAL OF CHEMISTRY
www.orientjchem.org
An International Open Access, Peer Reviewed Research Journal
ISSN: 0970-020 X
CODEN: OJCHEG
2023, Vol. 39, No.(5):
Pg. 1264-1271
This is an Open Access article licensed under a Creative Commons license: Attribution 4.0 International (CC- BY).
Published by Oriental Scientific Publishing Company © 2018
Design of Novel Thiohydantoin Derivatives and Exploration
Their Physico-Chemical Parameters
PRASHANT A. GOTMARE and SANJAY V. KOLHE
Department of Chemistry, Shri Shivaji Arts, Commerce and Science College,
Akot, Dist.Akola-444101, (Maharashtra), India.
*Corresponding author E-mail: prashantpatilchem2763@gmail.com
http://dx.doi.org/10.13005/ojc/390520
(Received: August 28, 2023; Accepted: October 11, 2023)
ABSTRACT
Thiohydantoin analogues was heterocyclic non-aromatic five membered cyclic compounds
obtained from aurones derivatives. In this article, we synthesized novel thiohydantoin derivatives and
exploration of physicochemical parameters like density, viscosity, ultrasonic velocity, intermolecular
free path, adiabatic compressibility etc. The structural elucidation of resultant compounds was done
on the basis
1
HNMR, IR, Mass etc. The present study revealed that, thiohydantoin analogues shows
more structure making capacity in DMSO than DMF.
Keyword: 2-Thiohydantoin, Physicochemical properties, Viscosity, Refractive index.
INTRODUCTION
2-Thiohydantoin is an important class
of compounds within chemistry. It is a sulphur
derivative of hydantoin which is obtained by replacing
the oxygen atom of carbonyl group by sulphur.
Thiohydantoin is a intermediate to synthesis of
many drugs
1-12
. In solid state thiohydantoin shows
π-π stacking, hydrogen bonding which is important
in pharmaceutical industries.
13-16
One of the most important things that
drew the attention of researchers to synthesized
thiohydantoin due to wide range of application like anti-
inflammatory, anti-ulcer
17
, antifungal, antibacterial
18
,
HIV
19
, hypolipidemic
20
, antimutagenic
21
, against
HSV
22
, anticarcinogenic
23
, on tuberculosis
24
and
pesticide
25
, derivatives of thiohydantoin are also
used as a fungicide
26
, N-phenyl derivative of
2-Thiohydantion shows antiparasitic activity against
Trypanosoma brucei species
27
.
K.H. Chikhalia et al.,
28
reported a series
of thiohydantoin derivatives having ethyl linked
3,4-dimethoxyphenylethyl thiourea derivatives with
styryl bridge possessing antibacterial properties as
well as anti HIV activity. Abubshait S.A.
29
synthesized
some 2-thiohydantoin drivatives and reported
anticancer and antimicrobial properties against
Gram-positive and Gram-negative bacteria. Kolhe
S.V.
30
prepared 2-thiohydantoin derivatives by mixing
aurones derivative with suitable thiourea by refluxing
with KOH and ethaonol as a solvent and reported
antimicrobial properties using microbes such as