Facile synthesis of SrO/CeO
2
/alginate nanocomposite for the
photocatalytic degradation of reactive red 195 dye and CO
2
capturing
Aisha
a
, Iqra Batool
a
, Afaf Almasoudi
b
, Shafia Iftekhar
c
, Syeda Aliya Shehzadi
d
,
Ammar Zidan
e
, Omar Makram Ali
f
, Muhammad Babar Taj
a,**
, Shahid Iqbal
g,*
,
Sajid Mahmood
g,h,***
, Toheed Akhter
i
, Heba Alshater
j
a
Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan
b
Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 42734, Jeddah, Saudi Arabia
c
Department of Chemistry, University of Sahiwal, Sahiwal 57000, Pakistan
d
Center of Interdisciplinary Research in Basic Sciences (CIRBS), Faculty of Sciences, International Islamic University, Islamabad 44000, Pakistan
e
Biomedical Engineering Department, College of Engineering and Technologies, Al-Mustaqbal University, Hillah 51001, Babil, Iraq
f
Department of Chemistry, College of Taraba, Taif University, Taif (Taraba), Saudi Arabia
g
Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute, University of Nottingham Ningbo China, Ningbo 315100, China
h
Functional Materials Group, Gulf University for Science and Technology, Mishref 32093, Kuwait
i
Department of Chemical and Biological Engineering, Gachon University, Seongnam 13120, Republic of Korea
j
Department of Forensic Medicine and Clinical Toxicology, Menoufia University, Shbien El-Kom, Egypt
HIGHLIGHTS
• The SrO/CeO
2
/ALG nanocomposite was constructed by using the Co-precipitation method.
• We found that strong electrostatic interaction exists in acidic media between anionic dye and SrO/CeO
2
/ALG surface.
• Under sunlight irradiation, about 93 % of the photodegradation efficiency of the dye was observed within 90 min.
• The prepared SrO/CeO
2
/ALG acting as a photocatalyst exhibits 4.31 and 2.98 mmol/g CO
2
capturing capacity.
A R T I C L E INFO
Keywords:
SrO/CeO
2
/ALG
Nanocomposite
CO
2
capturing
Reactive red 195 dye
ABSTRACT
The SrO/CeO
2
/ALG nanocomposite was successfully constructed by using the co-precipitation method and was
analyzed with zeta potential, FTIR, SEM, XRD and BET techniques. A common Azo dye, namely Reactive Red
195, widely utilized in the dyeing industry and causing environmental pollution, was chosen to examine the
photodegradation of SrO/CeO
2
/ALG nanocomposite, and it was shown that this dye could be successfully
degraded by prepared nanocomposite. Impacts of factors such as pH, contact time and effect of different con-
centrations of dye and catalyst, the effect of scavengers and the effect of hydrogen peroxide were investigated to
find out degradation efficiency. This SrO/CeO
2
/ALG nanocomposite was used for the photodegradation of
reactive red 195 dye and 93 % degradation efficiency was obtained at pH 3, 6 mg of catalyst concentration, dye
concentration of 10 ppm, and contact time of 90 min. Degradation kinetic studies were determined by applying
first-order and Langmuir-Hinshelwood reactions. The results exhibit a novel method for the synthesis of nano-
composite to effectively cause photodegradation of organic pollutants from wastewater and can be applied to
industrial manufacture. The mesoporous SrO/CeO
2
/ALG nanocomposite also captured 4.31 and 2.98 mmol/g
CO
2
at 25 and 40
◦
C temperatures, respectively.
* Corresponding author.
** Corresponding author.
*** Corresponding author. Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute, University of Nottingham Ningbo China, Ningbo
315100, China.
E-mail addresses: dr.taj@iub.edu.pk (M.B. Taj), shahidiqbal@hzu.edu.cn (S. Iqbal), sajidmahmood1987@yahoo.com (S. Mahmood).
Contents lists available at ScienceDirect
Materials Chemistry and Physics
journal homepage: www.elsevier.com/locate/matchemphys
https://doi.org/10.1016/j.matchemphys.2024.129894
Received 1 May 2024; Received in revised form 7 July 2024; Accepted 23 August 2024
Materials Chemistry and Physics 328 (2024) 129894
Available online 24 August 2024
0254-0584/© 2024 Elsevier B.V. All rights are reserved, including those for text and data mining, AI training, and similar technologies.