Journal of Inclusion Phenomena and Macrocyclic Chemistry 34: 57–68, 1999.
© 1999 Kluwer Academic Publishers. Printed in the Netherlands.
57
Synthesis, Characterization and Inclusion Properties
of an Iron(II) Polyimine Complex Derived from
2,6-Diacetylpyridine and an Aliphatic Polyamine
HENRIQUE E. TOMA
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, TULIO E. CHAVEZ-GIL and REGINALDO C.
ROCHA
Institutode Quimica, Universidade de São Paulo, CP 26077 CEP 05599-970, São Paulo, SP, Brazil
HERCÍLIO R. RECHENBERG
Institutode Física, Universidade de São Paulo, CP 66318 CEP 05315-970, São Paulo, SP, Brazil
(Received: 6 February 1998; in final form: 10 June 1998)
Abstract. A novel multibinding species has been obtained by attaching four aliphatic polyamine
chains to an iron(II)-polyimine centre, derived from 2,6-diacetylpyridine. Molecular simulations for
the complex corroborate the evidence from
1
H NMR spectroscopy of a symmetric structure, with
the four polyamines displaying a tetrahedral arrangement around the metal centre. The protonated
polyamine complex interacts with hexacyanoferrate(II) ions, leading to an inclusion compound
which has been characterized based on vibrational and Mössbauer spectroscopy, and on cyclic
voltammetry.
Key words: polyamine complex, iron(II)-polyimines, cyanoiron inclusion compound, Mössbauer
spectra
1. Introduction
Transition metal polyimine complexes have been used as versatile structural uni-
ties for building up supramolecular structures and devices [1–3]. By attaching
coordinating groups to the metal-polyimine centre, a novel type of multi-bridging
system can be devised for assembling polymetallic species [4] and for molecu-
lar recognition purposes. Here, we report on the synthesis and characterization
of an iron(II) polyimine complex exhibiting four aliphatic polyamine arms (Fig-
ure 1). The basic idea pursued in this work is centred on a new structural unity
containing four polyamine chains specially oriented for cooperative binding of
the amino/ammonium groups to donor/acceptor substrates. In fact, molecular
recognition of hexacyanometallates via outer-sphere association with protonated
cyclic polyamine ligands has already been reported in the literature [5–7]. For
this reason, a similar approach was attempted in this work by using the multi-
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