Citation: Shokraneh, N.; Alimi, M.;
Shahidi, S.-A.; Mizani, M.; Bameni
Moghadam, M.; Rafe, A. Textural and
Rheological Properties of Sliceable
Ketchup. Gels 2023, 9, 222. https://
doi.org/10.3390/gels9030222
Academic Editor: Aris Giannakas
Received: 15 February 2023
Revised: 8 March 2023
Accepted: 10 March 2023
Published: 14 March 2023
Copyright: © 2023 by the authors.
Licensee MDPI, Basel, Switzerland.
This article is an open access article
distributed under the terms and
conditions of the Creative Commons
Attribution (CC BY) license (https://
creativecommons.org/licenses/by/
4.0/).
gels
Article
Textural and Rheological Properties of Sliceable Ketchup
Nadia Shokraneh
1
, Mazdak Alimi
1,
*, Seyed-Ahmad Shahidi
1,
* , Maryam Mizani
2
, M. Bameni Moghadam
3
and Ali Rafe
4
1
Department of Food Science and Technology, Ayatollah Amoli Branch, Islamic Azad University,
Amol P.O. Box 6616935391, Iran
2
Department of Food Science and Technology, Science and Research Branch, Islamic Azad University,
Tehran P.O. Box 6616935391, Iran
3
Department of Statistics, Allameh Tabataba’i University, Tehran P.O. Box 1489684511, Iran
4
Department of Food Processing, Research Institute of Food Science and Technology (RIFST),
Mashhad P.O. Box 91775-1163, Iran
* Correspondence: ahooora_mazdak@yahoo.com or mazdak.alimi@iau.ac.ir (M.A.);
sashahidy@yahoo.com or sa.shahidi@iau.ac.ir (S.-A.S.)
Abstract: This study investigates the effect of different mixtures of gums [xanthan (Xa), konjac
mannan (KM), gellan, and locust bean gum (LBG)] on the physical, rheological (steady and unsteady),
and textural properties of sliceable ketchup. Each gum had an individually significant effect (p < 0.05)
on viscosity; however, the addition of Xa in combination with other gums had a greater effect on
viscosity. By increasing the use of Xa in ketchup formulations, the amount of syneresis decreased
such that the lowest amount of syneresis related to the sample prepared with 50% Xa and 50% gellan.
Although the use of different levels of gums did not have a significant effect on the brightness (L)
and redness (a) indices (p < 0.05), the use of different ratios of gums had a significant effect (p < 0.05)
on the yellowness (b) index. The effect of different levels of gums used had a significant effect
only on firmness (p < 0.05), and their effects on other textural parameters were not statistically
significant (p > 0.05). The ketchup samples produced had a shear-thinning behavior, and the Carreau
model was the best model to describe the flow behavior. Based on unsteady rheology, G’ was
higher than G” for all samples, and no crossover between G’ and G” was observed for any of
the samples. The constant shear viscosity (η) was lower than the complex viscosity (η*), which
showed the weak gel structure. The particle size distribution of the tested samples indicated the
monodispersed distribution. Scanning electron microscopy confirmed the viscoelastic properties and
particle size distribution.
Keywords: sliceable ketchup; gum; viscoelastic; rheological properties; syneresis
1. Introduction
Currently, market research shows a growing trend in ketchup consumption [1]. It is
predicted that in the period from 2021 to 2025, the market for this type of product will
have an annual growth of about 2.64%. Ketchup is a flavored product containing various
ingredients produced from a combination of fresh tomatoes or concentrates in the form of
puree or pastes with sweeteners, salt, vinegar, and spices [2]. This type of sauce is a non-
Newtonian semisolid material with a yield stress that exhibits thixotropic and viscoelastic
properties [3–6].
Ketchup is consumed with various foods such as ready meals, pasta, pizza, etc. One
of the most widely used uses for ketchup is with meat products, such as sausages, and
since these two types of foods are commonly consumed together, their combined use can
be a unique and attractive topic. Currently, a mixture of hydrocolloids is used to improve
physical and rheological properties and reduce costs [7]. Commercial ketchup usually is
thickened with tomato pulp powder [7], potato or corn starch [8,9], modified starch and
carboxymethylcellulose [10], guar, and carboxymethylcellulose and Xa [3,11].
Gels 2023, 9, 222. https://doi.org/10.3390/gels9030222 https://www.mdpi.com/journal/gels