Original Article
ANALYTICAL METHOD DEVELOPMENT AND VALIDATION OF FLAVOXATE HCL WITH RP-
HPLC
AAKRITI BHARDWAJ
1
, ROBIN KUMAR
2
, SHABNAM AIN
1*
, BABITA KUMAR
1
, QURRATUL AIN
1
1
Sanskar College of Pharmacy and Research, Ghaziabad-201001, Uttar Pradesh, India.
2
Principle Scientific Officer, IPC, Ghaziabad-201001,
Uttar Pradesh, India
*
Corresponding author: Shabnam Ain;
*
Email: shabnam.ain@sanskar.org
Received: 16 Oct 2024, Revised and Accepted: 12 Feb 2025
ABSTRACT
Objective: To verify analytical methods, suitability for its intended use is the goal of validation by Reverse Phase-High Performance Liquid
Chromatography (RP-HPLC) method.
Methods: A validated method for determining flavoxate hydrochloride was created using HPLC, which is a sensitive, exact, and straightforward
technique. The inertsilC18 (150 mm×4.6 mm, 5μm) is used in this approach. The buffer, which included 3g of 1-hexane sulphonic acid, 3 ml of
Orthophosphoric Acid (OPA) and 3 ml of Triethylamine (TMA), was combined with Acetonitrile (ACN) in a 650:350 ratio to form the mobile phase.
At 293 nm, Ultraviolet (UV) detection was done.
Results: The Retaining time for flavoxate HCl was found to be 2.43 min. It was discovered that the linearity range of flavoxate HCl was 800-1200 μg/ml,
and that the regression equation was y=17118x+80943. R 2 = 0.981 was found to be the linearity regression coefficient value. It was discovered that the
RSD for intra-and inter-day precision was less than 2 %. Flavoxate HCl was discovered to have Limit of Detection (LOD)-83.13734 and Limit of
Quantitation (LOQ)-251.9313 values of μg/ml and μg/ml, respectively. After statistical analysis, the results are deemed satisfactory.
Conclusion: This technique can be used to analyze bulk forms of the antimuscarinic medication flavoxate HCl with success.
Keywords: Accuracy, Flavoxate HCl, HPLC, Precision, Validation
© 2025 The Authors. Published by Innovare Academic Sciences Pvt Ltd. This is an open access article under the CC BY license (https://creativecommons.org/licenses/by/4.0/)
DOI: https://dx.doi.org/10.22159/ijpps.2025v17i4.53045 Journal homepage: https://innovareacademics.in/journals/index.php/ijpps
INTRODUCTION
Pharmaceutics is a subspecialty of pharmacy that studies how drugs
are made into dosage forms. It is a methodical process to obtain a
stable and effective formulation while taking into account all factors
necessary to preserve its quality. The development, formulation,
production, testing, and distribution of medication dosage forms are
within the multidisciplinary field of pharmaceutics in
pharmaceutical research. Physical pharmacy, pharmaceutical
technology, biopharmaceutics, pharmacokinetics, and
pharmaceutical analysis are only a few of the many topics it covers.
For quality assurance and control throughout the medication
research and production process, this field is essential [1-3].
Overactive Bladder (OAB) is a label for a group of urinary symptoms.
The need to urinate might come on suddenly and be difficult to
control. You may feel the need to urinate often during the day and
night. Urgency incontinence refers to the unintentional loss of pee.
Those who suffer from an OAB may experience feelings of insecurity.
Fortunately, there is a treatment available, an artificial
anticholinergic and antispasmodic drug called flavoxate HCl is used
to treat OAB syndrome and urine problems. It is used to treat
problems related to the bladder, including incontinence (leaking
urine), painful urination, frequent or urgent urination, increased
urination at night, and so on. Bladder infections, urethral irritation,
enlargement of the prostate and OAB are the most common causes
of these symptoms. Although flavoxate has a broad range of activity
against muscarinic acetylcholine receptors, it is thought to have less
ability to affect the central nervous system due to its highly polar
quaternary ammonium group, which makes it less likely to pass lipid
membranes like the Blood Brain Barrier (BBB) [4, 5].
Urine frequency and urgency are reduced and bladder capacity is
increased by flavoxate. Since its approval for usage in 1970, flavoxate
has been used in the US to treat OAB syndrome and cystitis symptoms
[6, 7]. Flavoxate was once marketed under the brand name Uri spas
and is available in 100 mg tablets in a number of generic variants.
Parasympathetic stimulation frequently causes adverse symptoms
such as dry mouth and eyes, headache, blurred vision, constipation,
urine retention, impotence, tachycardia and palpitations, anxiety,
restlessness, and in rare cases, agitation and delusions [8].
The ingredient "flavoxate hydrochloride" in flavoxate HCl relaxes the
muscles in the bladder. As a result, it aids in the prevention of
excessive or uncontrollably frequent urination. Drug use
observation research included 1800 patients who received flavoxate
(Spasuret®200) for urge incontinence over a two-week period.
Parameters for effectiveness and tolerance were established.
Flavoxate alone was used to treat a subset of 618 patients who did
not have benign prostatic hyperplasia or urinary tract infections.
Comparable to results from the full sample (1800 patients), the
bladder capacity increased by 36% at the onset of urge sensation.
The remaining urine volume was either steady or decreased in
89.2% of all individuals. In 1.8% of cases, undesirable side effects
were experienced. When flavoxate was taken four times a day (800
mg) as opposed to three times a day (600 mg), both groups
performed better. Flavoxate works effectively, is well tolerated, and
has no negative side effects or leftover urine issues [9].
Modern pharmaceutical and biological analyses rely on High-
Performance Liquid Chromatography (HPLC) as their primary
separation method because to its very successful separations and
generally high detection sensitivity. HPLC technique development
and validation are critical to research, manufacturing, and drug
discovery, among other applications [10-12]. Every facet of
validation-related performance characteristic is covered in the
International Conference on Harmonization (ICH) Guidelines for
HPLC method validation. These include testing for system
appropriateness, linearity, specificity, accuracy, precision, range and
limit of finding, and limit of detection [13-15].
In the absence of established ways, methods are created for new
products. A different approach to improve precision and durability
for current (non-pharmacopoeia) products is to cut costs and
International Journal of Pharmacy and Pharmaceutical Sciences
Print ISSN: 2656-0097 | Online ISSN: 0975-1491 Vol 17, Issue 4, 2025