Research article
Assessment of groundwater vulnerability to nitrates from agricultural
sources using a GIS-compatible logic multicriteria model
Boris Rebolledo
a, *
, Antonia Gil
a
, Xavier Flotats
b
, Jos
e
Angel S
anchez
c
a
Center of Research for Energy Resources and Consumption (CIRCE), C/Mariano Esquillor G omez 15, 50018, Zaragoza, Spain
b
GIRO Joint Research Unit IRTA-UPC, Department of Agrifood Engineering and Biotechnology, Universitat Politecnica de Catalunya, BarcelonaTECH, Parc
Mediterrani de la Tecnología, Building D4, E-08860, Castelldefels, Barcelona, Spain
c
Departamento de Ciencias de la Tierra,
Area de Geodin amica, Edificio de Geol ogicas Pedro Cerbuna, 12, 50009, Zaragoza, Spain
article info
Article history:
Received 5 October 2015
Received in revised form
26 January 2016
Accepted 30 January 2016
Available online xxx
Keywords:
Groundwater vulnerability
Risk mapping
Nitrate pollution
Logic Scoring of Preferences (LSP)
Aragon (Spain)
abstract
In the present study an overlay method to assess groundwater vulnerability is proposed. This new
method based on multicriteria decision analysis (MCDA) was developed and validated using an appro-
priate case study in Aragon area (NE Spain). The Vulnerability Index to Nitrates from Agricultural Sources
(VINAS) incorporates a novel Logic Scoring of Preferences (LSP) approach, and it has been developed
using public geographic information from the European Union. VINAS-LSP identifies areas with five
categories of vulnerability, taking into account the hydrogeological and environmental characteristics of
the territory as a whole. The resulting LSP map is a regional screening tool that can provide guidance on
the potential risk of nitrate pollution, as well as highlight areas where specific research and farming
planning policies are required.
© 2016 Elsevier Ltd. All rights reserved.
1. Introduction
The increasing international concern about nutrient overload
into the environment has resulted in the introduction of strict
regulations for the protection of water resources. Within this
context, groundwater contamination by nitrates (NO
3
-
) from agri-
cultural sources is one of the most widespread threats worldwide
(Addiscott and Benjamin, 2004; Karr et al., 2001; Weyer et al.,
2001). Due to this threat the EU drew up the Nitrate Directive 91/
676/EC concerning the protection of waters against nitrate from
agricultural sources.
Since the EU Nitrate Directive was adopted, important differ-
ences have been observed in the methods and approaches used to
identify Nitrate Vulnerable Zones (NVZs) (European Commission,
2013). Although criteria for identifying the NVZs were established
in the Nitrate Directive, the specific procedure for the delimitation
of these vulnerable areas is still unclear. Furthermore, recent
research has shown that an inadequate designation of NVZs can
generate unsatisfactory results in the contamination reduction of
affected water bodies (Arauzo and Martínez-Bastida, 2015; Arauzo
and Valladolid, 2013; Worrall et al., 2009).
In Spain, the regional administrations are responsible for iden-
tifying NVZs from agricultural practices. In general, analysis of
water quality data from networks of monitoring stations has been
used to designate vulnerable zones, and administrative boundaries
and groundwater bodies have been used to delineate the shape of
these areas. Furthermore, the emphasis on the evidence of envi-
ronmental damage, rather than on a proactive planning, can hinder
successful conservation of water resources. Therefore, it is neces-
sary to develop a more rational, rigorous and systematic approach.
Until now, several methods for groundwater vulnerability and
risk mapping have been proposed. They range from complex
deterministic models of the physical, biological and chemical ni-
trate leaching processes occurring in vadose zone and saturated
zone (De Paz and Ramos, 2004; Lasserre et al., 1999; Ledoux et al.,
2007; Srinivasan and Arnold, 1994), to methods that are based on
overlay and index techniques to obtain a final vulnerability score.
Index methods are based on combining rated maps of various
physiographic factors (e.g., depth to water table, aquifer type, soil
organic carbon content) of the region by assigning a subjective
numerical score to each factor. Models of index methods include
DRASTIC (Aller et al., 1987); GOD (Foster, 1987); AVI (Van
Stempvoort et al., 1993); EPIK (Doerfliger et al., 1999); SINTACS * Corresponding author.
E-mail address: brebolle@unizar.es (B. Rebolledo).
Contents lists available at ScienceDirect
Journal of Environmental Management
journal homepage: www.elsevier.com/locate/jenvman
http://dx.doi.org/10.1016/j.jenvman.2016.01.041
0301-4797/© 2016 Elsevier Ltd. All rights reserved.
Journal of Environmental Management 171 (2016) 70e80