Optics Communications 454 (2020) 124437
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Optics Communications
journal homepage: www.elsevier.com/locate/optcom
Efficiency improvement of a silicon-based thin-film solar cell using
plasmonic silver nanoparticles and an antireflective layer
Afsaneh Asgariyan Tabrizi
a,∗
, Ali Pahlavan
b
a
Department of Engineering, Sari Branch, Islamic Azad University, Sari, Iran
b
Department of Physics, Sari Branch, Islamic Azad University, Sari, Iran
ARTICLE INFO
Keywords:
Silicon
Thin films
Solar cells
Silver nanoparticles
Absorption
Efficiency
Fill-factor
Plasmonics
ABSTRACT
This paper presents a silicon thin-film solar cell (TFSC) integrated with the silver nanoparticles. It consists of
anti-reflection, absorption and reflective layers in which the anti-reflective layer is made of pyramids of TiO
2
.
The purpose of this structure is to allow sunlight to enter the cell at any angle with the minimum reflection
and absorption in the wavelength range of 300–1100 nm. The absorbing layer is composed of silicon and
when sunlight enters this layer, the molecular bonds break down and release many electrons due to its high
absorption coefficient. In this layer, silver spherical nanoparticles are placed to increase the absorption of solar
energy by the localized surface plasmon resonances, which will increase the efficiency of the TFSC. The last
layer of the structure is a reflective surface of aluminum, which aims to reflect the light into the upper layer
to enhance its absorption. We will calculate the key performance metrics for a solar cell such as short-circuit
current, open-circuit voltage, fill-factor, and photovoltaic efficiency considering the effects of recombination
between silicon substrate and other materials. The numerical results based on the finite-difference time-domain
method reveal that the proposed structure has much more absorption due to the anti-reflection layer and the
presence of silver nanoparticles that leads to light scattering, light localization, and guided mode excitation
compared to conventional TFSC. Our simulations based on the finite-element method show the presented TFSC
integrated with silver nanoparticles has a fill-factor of 0.82 and an efficiency of 16.18%.
1. Introduction
A solar cell is a photovoltaic component that converts solar energy
into an electric current. This is done using semiconducting materials
with photovoltaic properties [1]. The research groups have focused
on the principles and concepts of new photovoltaics including thin-
film [2], organic [3], plasmonic [4–7], dye-sensitized [8–11], and
photonic crystal [12,13] solar cells with the goal of reducing manu-
facturing costs and used materials (consumables), as well as increasing
the efficiency of solar cells. When incorporating nanophotonic elements
similar to metallic nanoparticles with plasmon resonances tuned to
efficiently scatter the light into the absorbing layer, or nanotextured
surface anti-reflection coatings to decrease undesirable back reflections
that degrade cell performance, solar cell efficiency can be dramatically
enhanced [7,14,15]. In recent years, thin-film silicon solar cells have
attracted much attention due to their low manufacturing costs, but
their efficiency is relatively low compared to other structures [16].
The main problem is very low absorption at the edge of the con-
duction band. Therefore, advanced schemes have been proposed to
improve absorption based on light trapping in the active layer of
a solar cell. In general, light-trapping methods are divided into (1):
∗
Corresponding author.
E-mail addresses: asgariyan@gmail.com (A.A. Tabrizi), pahlavan@iausari.ac.ir (A. Pahlavan).
reduce the reflection coefficient of the upper surface, and (2): increase
the optical length inside the cell [17]. Various techniques have been
presented by research groups to trap the sunlight including the use
of anti-reflection coatings, rough surfaces [18,19], window grids [20],
photonic crystals [21,22] and plasmon-based metallic nanoparticles [5,
23,24]. Among the above-mentioned methods, many studies are based
on plasmonic nanoparticles. Indeed, plasmonic approach is one of the
most desirable methods for improving localized light absorption [25,
26]. The study of metal nanoparticles in the upper layer of the solar
cells shows a significant increase in the absorption of light [7]. It
is caused by the scattering effect due to the excitation of surface
plasmons. Increasing the absorption leads to lower recombination rate,
higher open circuit voltage, higher conversion efficiency, and even new
solar-cell designs. Since plasmonic metal nanostructures were used in
the thin film solar cells, this led to strong light trapping due to the
strong interaction of light in plasmonic nanostructures and surrounding
media. Various structures have been proposed to increase the length of
the optical pathway within the cell. Using structures with a periodic
lattice is a simple way to increase the effective optical length because
it can be contracted at both cell surfaces and increase the absorption
https://doi.org/10.1016/j.optcom.2019.124437
Received 5 July 2019; Received in revised form 13 August 2019; Accepted 19 August 2019
Available online 22 August 2019
0030-4018/© 2019 Published by Elsevier B.V.