Journal of Civil Engineering and Environmental Technology
p-ISSN: 2349-8404; e-ISSN: 2349-879X; Volume 3, Issue 5; April-June, 2016, pp. 426-429
© Krishi Sanskriti Publications
http://www.krishisanskriti.org/Publication.html
Effect on Compressive Strength of Concrete by
Partial Replacement of Cement with Nano
Titanium Dioxide and Nano Calcium Carbonate
Shivanshu Mishra
1
and Archana Tiwari
2
1
Student Department of Civil Engineering, Madhav Institute of Technology and Science Gwalior, India
2
Department of Civil Engineering, Madhav Institute of Technology and Science Gwalior, India
E-mail:
1
shivanshumishra07@gmail.com,
2
archana62in@gmail.com
Abstract—In this paper resulting change in the compressive strength
of the concrete due to the partial replacement of cement by Nano-
titanium di oxide and Nano-calcium carbonate are studied. Two types
of concrete were prepared by replacing cement by Nano titanium
dioxide and Nano calcium carbonate. Eight sets of specimens are
casted and compared with the control specimen. In both types of
concrete 0.5%, 1%, 1.5%, 2% by weight of cement is replaced by
Nano material. In case of concrete prepared by using
2
the
maximum compressive strength is achieved at 2% replacement and in
case of concrete prepared by using ܥܥ
3
the maximum strength is
achieved at 0.5% replacement. As compared to the control concrete
an increase of 38.5% is achieved in 28 days compressive strength in
2
concrete and 38.4% in case of ܥܥ
3
concrete. The
characteristic of the Nano-
2
and Nano-ܥܥ
3
containing
concrete is examined at the 7, 14, and 28 days
1. INTRODUCTION
Concrete is the spine of the construction industry. The
concrete in the pavement is subjected to various types of loads
in a repeated form due to which various types of failure occurs
in the concrete such as cracks due to over load and flexure.
Flexural fatigue also responsible for failure of concrete
pavement which can be reduced by use of nano material.
Maximum improvement in flexural fatigue strength is reported
best in concrete containing nano
ଶ
in amount of 1% by
weight of binder[1].Most uniform dispersion of hydration
products of cement is achieved at a small content of nano
ଶ
, it accelerates the hydration at early age ages as indicated
by heat of hydration [2].Cement replacement up to 20% by
mixture of nano and micro ܥܥ
ଷ
resulted in similar
enhanced mechanical properties. Benefits of accelerated early
age hydration through additional nucleation sites and
enhanced particle packing density achieved [3]. Ali nazari
reported decrease in setting time of cement mortar with
increase in nano
ଶ
and improvement in flexural and tensile
strength with the addition of Nano
ଶ
up to 1% at all ages of
concrete [8,11]. Reduction in 28 days compressive strength of
mortar is reported when
ଶ
increases. Inclusion of
ଶ
in
cement mortar did not increase the 28 days compressive
strength [10]. There are various nano materials available
which are used frequently because of their dispersion quality
such as carbon nano tubes(CNTs) and carbon nano fibers
which provide reinforcement to the concrete and other
particles such as nano
ଶ
, nano
ଶ
, nano ܣ
ଶ
ଷ
, nano
ܨ
ଶ
ଷ
, nano ܥܥ
ଷ
etc. Nano-titanium dioxide and nano-
calcium carbonate are used in this study. Small amount of
2
results in effective increase in strength of the concrete
thus it seems beneficial to use this material in the construction
work by simply adding it in to the concrete. Nano calcium
carbonate in the concrete can also be used similarly.
2. MATERIALS AND EXPERIMENTS
2.1 Materials
The materials used are given below.
Cement.
Portland Pozzolana Cement (prism) Fly ash based conforming
to (IS: 1489-1991). The physical properties of cement were
obtained by conducting appropriate tests.
Specific gravity is 2.9
Fineness- 2% retaining on 90 micron sieve
Coarse aggregate
Locally available 20 mm and 12.5mm size crushed granite
with specific gravity 2.70 and water absorption 0.1%.
Fine aggregate
River sand was used and found to be Zone 2 with its specific
gravity 2.60 and water absorption 1%.
Water
Water used was clean drinking fresh water (pH value 6-7)
which is free from impurities and therefore, can be used for
concrete mixing.