Vol.:(0123456789)
International Journal of Thermophysics (2020) 41:168
https://doi.org/10.1007/s10765-020-02748-y
1 3
NANOPARTICLE-ENHANCED IONIC LIQUIDS
Investigation of Iron Oxide‑Based Ionanofluids and Ionic
Liquids by Ultrasonic Sound Velocity Method
Aswathy Joseph
1
· Pankajakshan Radhakrishnan Nair
2
· Suresh Mathew
1,2
Received: 14 September 2020 / Accepted: 30 September 2020
© Springer Science+Business Media, LLC, part of Springer Nature 2020
Abstract
Measurement of ultrasonic sound velocity in ionic liquids and ionanofluids can give
important information about the liquid structure, nanoparticles interactions, effect of
water, extent of intermolecular association and the kinetics of molecular processes.
Here, the acoustic properties of certain pyridinium-based ionic liquids and their
iron oxide-based ionanofluids have been studied using a nanofluid interferometer
device. In the ionanofluids, the sound velocity was observed to decrease anisotropi-
cally with increase in temperature. The magnetic dipolar interactions among the iron
oxide nanoparticles, the nature of IL’s anion and cation as well as sound wave fre-
quency also influenced the sound velocity in the ionanofluid. The effects of sound
frequency, temperature and the percentage of water content on the sound velocity in
certain pure ionic liquids have also been investigated here.
Keywords 1-Butylpyridinium bromide · Ionanofluid · Ionic liquids · Nanofluid
interferometer · Ultrasonic sound velocity
1 Introduction
The use of ionic liquids (ILs) for manufacturing nanofluids (NFs) opens up new
possibilities in the field of nanoparticles enhanced ionic liquids (NEILs) for
advanced heat transfer applications [1–5]. Ionic liquids (IL) when used as carrier
This article is part of the Special Issue on Nanoparticle-enhanced Ionic Liquids.
* Suresh Mathew
sureshmathewmgu@gmail.com
Pankajakshan Radhakrishnan Nair
ammrcmgu@gmail.com
1
School of Chemical Sciences (SCS), Mahatma Gandhi University, Kottayam, Kerala 686 560,
India
2
Advanced Molecular Materials Research Centre (AMMRC), Mahatma Gandhi University,
Kottayam, Kerala 686 560, India