Original Article
DESIGN AND IN SILICO EVALUATION OF PHENOXY ACETAMIDE DERIVATIVES AS POTENTIAL
ANTIDIABETIC AGENTS
INDHUMATHI S.
1
, S. SREE NITHI
1
, GOBIANANTH
1
, MOHD ABDUL BAQI
2*
, N. VENKATHESHAN
1
,
GANESH MEENA
2
, KOPPULA JAYANTHI
1*
1
Department of Pharmaceutical Chemistry, Arulumigu Kalasalingam College of Pharmacy, Kalasalingam Academy of Research and
Education, Krishnan Koil, Tamil Nadu, India.
2
Department of Pharmaceutics, Arulumigu Kalasalingam College of Pharmacy, Kalasalingam
Academy of Research and Education, Krishnan Koil, Tamil Nadu, India.
3
Department of Pharmaceutical Chemistry, Chemistry, Arulumigu
Kalasalingam College of Pharmacy, Kalasalingam Academy of Research and Education, Krishnan Koil, Tamil Nadu, India
*
Corresponding author: Koppula Jayanthi;
*
Email: jayanthi.k@akcp.ac.in
Received: 06 May 2025, Revised and Accepted: 04 Jul 2025
ABSTRACT
Objective: This study explores the interactions of phenoxy acetamide derivatives with AMP-activated protein kinase (AMPK), a key enzyme in
metabolic regulation. The goal is to evaluate the AMPK activation potential of these compounds using in silico approaches.
Methods: Molecular docking was performed using the Glide module to assess binding affinity. Binding free energy (ΔG_bind) was calculated using
the MM-GBSA method, and pharmacokinetic profiles were evaluated via ADME predictions using QikProp.
Results: Among the tested compounds, 3-chlorophenyl phenoxy acetamide (compound 5) exhibited the highest XP-docking score of –5.22 kcal/mol
and a ΔG_bind of –97.78 kcal/mol, indicating strong binding with the AMPK active site. Key interactions included hydrogen bonding with residues
PRO127, MET84, ARG117, and TYR120. ADME analysis revealed that all compounds showed low CNS penetration (QPlog BB<–1) and acceptable
intestinal absorption (Caco-2>300 nm/s).
Conclusion: Compound 5 demonstrates significant AMPK activation potential and favorable ADME properties, suggesting its promise as a lead
compound for type II diabetes therapy.
Keywords: Molecular docking, MM-GBSA, Phenoxy-acetamide, AMPK, ADME, Type II diabetes
© 2025 The Authors. Published by Innovare Academic Sciences Pvt Ltd. This is an open access article under the CC BY license (https://creativecommons.org/licenses/by/4.0/)
DOI: https://dx.doi.org/10.22159/ijap.2025v17i5.54892 Journal homepage: https://innovareacademics.in/journals/index.php/ijap
INTRODUCTION
Diabetes mellitus is a chronic metabolic disorder characterized by
persistent hyperglycaemia resulting from defects in insulin secretion,
insulin action, or both. It poses a significant global health challenge,
affecting over 537 million adults as of 2021, with projections estimating
an increase to 643 million by 2030 and 783 million by 2045 [1]. Among
its types, type 2 diabetes mellitus T2DM accounts for more than 90% of
all diabetes cases and is predominantly associated with insulin
resistance and relative insulin deficiency [2]. The pathophysiology of
T2DM involves a complex interplay of impaired insulin signaling,
reduced glucose uptake by peripheral tissues such as skeletal muscle and
adipose tissue, hepatic overproduction of glucose, and chronic
inflammation [3]. If left untreated, T2DM can lead to serious
complications, including cardiovascular disease, nephropathy,
neuropathy, retinopathy, and increased mortality. Globally, diabetes was
responsible for approximately 6.7 million deaths in 2021, underscoring
the urgent need for effective and sustainable therapeutic strategies.
Management of T2DM typically involves lifestyle interventions and
pharmacological therapy. Insulin, discovered in the early 1920s, was the
first antidiabetic drug and remains essential, particularly for type 1
diabetes. The introduction of oral antidiabetic agents, notably
sulfonylureas and biguanides such as metformin, expanded treatment
options significantly. Metformin continues to be the first-line treatment
due to its efficacy, safety profile, and affordability [4]. In recent years,
new drug classes have emerged, targeting diverse mechanisms of
glucose regulation. These include thiazolidinediones, which enhance
insulin sensitivity; DPP-4 inhibitors, which prolong incretin hormone
activity; SGLT2 inhibitors, which reduce renal glucose reabsorption; and
GLP-1 receptor agonists, which enhance insulin secretion and promote
weight loss. Despite these advancements, the therapeutic landscape is
still challenged by issues such as drug resistance, adverse effects, and the
inability to fully prevent disease progression in many patients. Given the
multifactorial nature of T2DM, there remains a pressing need to develop
new therapeutic agents that are safer, more effective, and capable of
targeting multiple pathways involved in disease progression. In this
context, in silico approaches have become an essential tool in modern
drug discovery, enabling researchers to identify and optimize lead
compounds rapidly and cost-effectively [5]. These computational
techniques facilitate virtual screening and prediction of molecular
interactions with key antidiabetic targets, streamlining early-phase drug
development. Phenoxy acetamide derivatives have recently gained
attention due to their structural versatility and broad biological
activities, including antioxidant, anti-inflammatory, and antidiabetic
potential [6]. Their chemical framework allows for functional
modifications that may enhance binding affinity and selectivity toward
metabolic targets. One particularly promising target in the treatment of
T2DM is AMP-activated protein kinase (AMPK), a key regulator of
cellular energy homeostasis. Activation of AMPK enhances glucose
uptake, fatty acid oxidation, and insulin sensitivity while suppressing
hepatic gluconeogenesis. Recent evidence also suggests that AMPK
activation can stimulate pancreatic β-cell function and promote insulin
secretion, providing a dual therapeutic benefit. Therefore, the
identification of small molecules capable of activating AMPK offers a
strategic approach to improving glycemic control and preserving β-cell
function in diabetic patients. The present study aims to design and
evaluate novel phenoxy acetamide derivatives using in silico
methodologies to identify promising candidates for antidiabetic therapy.
Special emphasis is placed on the interaction of these compounds with
AMPK, with the goal of identifying activators that can enhance insulin
production and improve metabolic regulation. Molecular docking studies
will be employed to investigate their binding affinity and potential
efficacy. The findings of this research are expected to contribute to the
development of more effective therapeutic agents for managing type 2
diabetes mellitus.
MATERIALS AND METHODS
Protein preparation
The protein structure was prepared using the Protein Preparation
Wizard at physiological pH (7.0). Key catalytic residues, such as
lysine, were assigned standard protonation states appropriate for
International Journal of Applied Pharmaceutics
ISSN- 0975-7058 Vol 17, Issue 5, 2025