American Journal of Heterocyclic Chemistry
2025, Vol. 10, No. 2, pp. 41-54
https://doi.org/10.11648/j.ajhc.20251002.12
*
Corresponding author:
Received: 13 September 2025; Accepted: 22 September 2025; Published: 14 October 2025
Copyright: © The Author(s), 2025. Published by Science Publishing Group. This is an Open Access article, distributed
under the terms of the Creative Commons Attribution 4.0 License (http://creativecommons.org/licenses/by/4.0/), which
permits unrestricted use, distribution and reproduction in any medium, provided the original work is properly cited.
Research Article
Triple Cascade Synthesis of Dihydropyrimidones Using
Lawsone and Heterocyclic Scaffolds with a Zinc Acetate
Catalyst: Dyeing Efficiency on Nylon and Polyester Fabrics
Nilam Patel
1
, Prashant Kumdale
2, *
, Sneha Kulkarni
3
, Paresh Patel
4
,
Suchitra Savant
1
1
Department of Chemistry, VanitaVishram Women’s University, Surat, India
2
Department of Chemistry, Shivneri College Shirur Anantpal, Dist, Latur India
3
Department of Chemistry, KLS ViShwanathro Deshpande Institute of Technology, Haliyal, India
4
Department of Chemistry, Uka Tarsadia University, Bardoli, India
Abstract
This report presents an efficient triple cascade protocol for synthesizing new disperse dyes derived from different heterocyclic
scaffolds, urea, and lawsone. This study proposes a novel modification protocol for disperse dyes that enhances their affinity
for nylon substrates through the use of Zinc acetate catalyst, without inducing structural changes in the nylon fibers. Zinc
acetate, which is favored due to its low-priced, low toxicity, and environmental benefits, has emerged as a valuable catalyst for
this reaction. Triple cascade reactions (TCRs) represent a pivotal strategy in modern synthetic chemistry for the efficient
construction of diverse organic molecules, owing to their high atom economy, operational simplicity, and environmentally
benign nature. The recently synthesized disperse dyes demonstrate excellent dyeing properties on mutually nylon and polyester
fibers. The Experimental finding demonstrated that the newly established dispersed dye had a significant effect on the dyeing
performance and overall coloration properties of the substrates. The novel dyes show superior dyeing properties compared to
lawsone, especially in term of vibrant shades, higher affinity, improved adsorption capacity and advanced tinctorial strength.
Additionally, the percentage exhaustion, fixation, color strength (K/S), washing fastness & sublimation fastness properties are
notably better in nylon-dyed samples than in polyester. These findings highlight the significant potential of these novels
disperse dyes for nylon & polyester fiber. With commercialization, these dyes could provide a better alternative to conventional
disperse dyes, offering broader benefits across various industries.
Keywords
Triple Cascade Reaction, Disperse Dyes, Fastness, Color Strength (K/S), Exhaustion and Fixation