Journal of Ecology and the Natural Environment Vol. 3(5), pp. 168-175, May 2011
Available online at http://www.academicjournals.org/jene
ISSN 2006- 9847 ©2011 Academic Journals
Full Length Research Paper
Biosorption of heavy metals by immobilized and dead
fungal cells: A comparative assessment
B. Hemambika, M. Johncy Rani and V. Rajesh Kannan*
Rhizosphere Biology Laboratory, Department of Microbiology, School of Life Sciences, Bharathidasan University,
Tiruchchirappalli – 620 024, Tamil Nadu, India.
Accepted 10 January, 2011
Heavy metal resistant fungi were isolated from an electroplating industrial effluent samples that uses
copper, cadmium and lead for plating. These isolates were tested to evaluate their applicability for
heavy metal removal from industrial wastewaters. Initially the physico-chemical parameters of the
samples were analyzed. The optimum conditions of pH, biomass concentration and heavy metal
concentration were determined for the microbial growth on biosorbents and correlated with heavy
metal removal. The observed conditions were applied for the biosorption process in immobilized and
dead fungal cells. The biosorption of immobilized cells of Aspergillus sp. was 60.94% of Cu, Penicillium
sp. was 97.21% of Cd and Cephalosporium sp. was 73.27% of Pb; whereas the dead cells of Aspergillus
sp. was 46.91% of Cu, Penicillium sp. was 95.27% of Cd and Cephalosporium sp. was 70.67% of Pb.
Experimental results reveal that all the immobilized isolates have potential application for the removal
of Cu, Cd and Pb from industrial wastewater than the dead fungal cells.
Key words: Heavy metal, fungal sorption, optimization, dead fungal cells, immobilization
INTRODUCTION
Developmental progress in an industry is a major criterion
of any country. Industrial creations have emerged as one
of the world’s most dynamic and economic sectors,
offering vast opportunities for cultural, social and
economic development. Today, India is one of the top ten
indus-trialized countries of the world (Guillén, 2003).
Regional industrial production is outstripping global
growth from one side and several highly polluting
industries are growing more rapidly in another side.
Because of the rapid growth in urbanization and indus-
trialization, the impact of foreign direct investment (FDI)
due to environmental terms has largely been negative.
The current pattern of industrial activity alters the natural
flow of materials and introduces novel toxic chemicals
into the environment (Faisal and Hasnanin, 2004). Heavy
metal release to the environment has been increasing
*Corresponding author. E-mail: uvrajesh@gmail.com. Tel: +91-
431-2407082. Fax: +91- 431-2407045.
continuously because of industrial activities and techno-
logical development and poses a significant threat to the
environment, public and soil health. Contamination of
agricultural soil with heavy metals is a major problem on
industrial and defense related sites all over the world
(Parameswari et al., 2010). Heavy metals include
cadmium, lead, chromium, copper and nickel, which
contaminate the soils, ground water, sediments and
surface waters are extremely toxic to biological and
ecological systems. The heavy metals are released due
to the discharge of effluent into the environment by a
large number of processes such as electroplating, leather
tanning, wood preservation, pulp processing, steel
manufacturing, etc. The concentration levels of these
heavy metals vary widely in the environment. Heavy
metals have a critical concern to human health and
environmental issues due to their high occurrence as a
contaminant, present in soluble form that are extremely
toxic to biological systems, and the classification of
several heavy metals as carcinogenic and mutagenic
(Alloway, 1995; Diels et al., 2002). Moreover, the metals