ORIGINAL PAPER Migration of geothermal fluids in extensional terrains: the ore deposits of the Boccheggiano-Montieri area (southern Tuscany, Italy) Domenico Liotta Æ Giovanni Ruggieri Æ Andrea Brogi Æ Paolo Fulignati Æ Andrea Dini Æ Isabella Nardini Received: 10 June 2008 / Accepted: 15 December 2008 / Published online: 13 January 2009 Ó Springer-Verlag 2009 Abstract An integrated study based on fluid inclusion, d 18 O composition and structural analyses was carried out on a Pliocene fossil hydrothermal system, located to the South of the present active Larderello geothermal field, in the Boccheggiano-Montieri area. The study area is typified by mineralized cataclastic levels related to Late Oligo- cene–Early Miocene thrust surfaces, and to the following two generations of normal faults of Miocene and Pliocene ages, respectively. Within the damage zone of the Pliocene Boccheggiano fault, the mineralization is mainly made up of quartz and pyrite. Quartz ? Pb–Zn sulfides, or quartz ? Pb–Zn sulfides ? fluorite ? carbonates assem- blages occur instead in the older cataclastic levels. Two generations of liquid-rich fluid inclusions were recognized in quartz and fluorite: the first one, with homogenization temperatures ranging between 172 and 331°C and salinity between 0.0 and 8.8 wt.% NaCl equiv. , records the early stage of hydrothermal activity. The second generation of fluid inclusions documents a later stage, with homogeni- zation temperature from 124 to 288°C and salinity from 0.2 to 1.9 wt.% NaCl equiv. . Fluid inclusions analyses also indicate that mixing of fluid with distinct salinities and/or temperatures was a widespread process during the early stage, and that fluid temperatures decreased moving from the Boccheggiano fault toward the more distal and older cataclastic levels. The d 18 O values of water in equilibrium with hydrothermal quartz, which range from -5.7 to -0.1%, are related to the circulation of meteoric water mixed with saline water that leached the evaporite level and enriched in d 18 O through water–rock interaction, and/ or with magmatically derived fluids. Results indicate that the damage zone of the Pliocene Boccheggiano fault rep- resented the main channel for the flow of meteoric water, which was heated at depth, then mixed with high salinity fluids, and finally ascend to infiltrate along the older cataclastic levels. Our results, based on fluid inclusions, oxygen isotopic compositions and structural analyses indicate that a single fluid flow path run through the damage zone of the Boccheggiano fault and the older cataclasites, which were thus hydraulically connected. Keywords Fluid inclusions  Ore deposits  Structural geology  Fault rocks  Geothermics  Northern Apennines  Tuscany Introduction The understanding of fluid migration through the upper crust represents a continuous task for successful exploration D. Liotta (&) Dipartimento di Geologia e Geofisica, Universita ` di Bari, Via Orabona 4, 70125 Bari, Italy e-mail: d.liotta@geo.uniba.it G. Ruggieri CNR-Istituto di Geoscienze e Georisorse, Via La Pira 4, 50121 Florence, Italy A. Brogi Dipartimento di Scienze della Terra, University of Siena, Via Laterina 8, 53100 Siena, Italy P. Fulignati Dipartimento di Scienze della Terra, University of Pisa, Via S.Maria 53, 56100 Pisa, Italy A. Dini  I. Nardini CNR-Istituto di Geoscienze e Georisorse, Via Moruzzi 1, 56125 Pisa, Italy 123 Int J Earth Sci (Geol Rundsch) (2010) 99:623–644 DOI 10.1007/s00531-008-0411-3