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Indo American Journal of Pharmaceutical Research, 2013 ISSN NO: 2231-6876
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INDO AMERICAN
JOURNAL OF
PHARMACEUTICAL
RESEARCH
SYNTHESIS, CHARACTERIZATION AND IN-VITRO ANTIMICROBIAL STUDY OF
SERIES OF 1-((SUBSTITUTED ARYL/ALKYL)SULFONYL)-4-TOSYLPIPERAZINES
Mohan N R
1
, Sreenivasa S
1*
, Manoj Kumar K E
1
, Anitha H C
1
, Madhu Chakrapani Rao T
2
,
Thippeswamy B S
3
, Vijay K Gowda
4
1
Department of Studies and Research in Chemistry, Tumkur University, Tumkur - 572 103, Karnataka, INDIA
2
Tadimety Aromatics Pvt. Ltd, Hirehalli Industrial Area, Tumkur - 572 168, Karnataka, INDIA
3
Department of Pharmacology, Sree Siddaganga College of Pharmacy, Tumkur - 572 102, Karnataka, INDIA
4
Department of Studies and Research in Environmental Science, Tumkur University, Tumkur-572 103, Karnataka, INDIA
Corresponding author
Dr. Swamy Sreenivasa
Associate Professor and Chairman
Department of Studies and Research in Chemistry
Tumkur University, Tumkur -572103
Karnataka (state), INDIA
drsreenivasa@yahoo.co.in
drsreenivasa@tumkuruniversity.in
Copy right © 2013 This is an Open Access article distributed under the terms of the Indo American journal of Pharmaceutical
Research, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
ARTICLE INFO ABSTRACT
Article history
Received 14/11/2013
Available online
30/12/2013
Keywords
Bis-sulfonylpiperazine ,
Trifluroacetic acid,
Antimicrobial.
A new series of bis-sulfonyl piperazines were taken up for synthesis by inserting two sulfonyl
groups at 1
st
and 4
th
position of piperazine in search of potent antimicrobial agents. An
imperative intermediate 1-tosylpiperazine was accomplished through deprotection of di-tert-
butyl dicarbonate group from 4-tosylpiperazine-1-carboxylate by using trifluroacetic acid.
Further 1-tosylpiperazine upon electrophilic substitution reaction using appropriate
substituted sulfonyl chlorides gave 1-((substituted aryl/alkyl)sulfonyl)-4-tosylpiperazines 8a-k
as targeted series of bis-sulfonyl piperazines. The design, synthesis, FT-IR,
1
H NMR,
13
C
NMR, LC-MS spectral characterizations, elemental analysis and their in-vitro antimicrobial
potency is discussed in this communication. Compounds 8f, 8j and 8k are proved to be potent
antimicrobial agents.
Please cite this article in press as Mohan N R et al., Synthesis, characterization and in-vitro antimicrobial study of series of 1-
((substituted aryl/alkyl)sulfonyl)-4-tosylpiperazines. Indo American Journal Of Pharm Research. 2013:3(12).