Hindawi Publishing Corporation
Advances in Condensed Matter Physics
Volume 2013, Article ID 821073, 5 pages
http://dx.doi.org/10.1155/2013/821073
Research Article
Electrical Transport Properties of (Bi
1.6
Pb
0.4
Sr
2
Ca
2
Cu
3
O
10
)/Ag
Tapes with Different Nanosized MgO
Nabil A. A. Yahya and R. Abd-Shukor
School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia
Correspondence should be addressed to R. Abd-Shukor; ras@ukm.my
Received 6 July 2013; Revised 4 November 2013; Accepted 4 November 2013
Academic Editor: R. N. P. Choudhary
Copyright © 2013 N. A. A. Yahya and R. Abd-Shukor. his is an open access article distributed under the Creative Commons
Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is
properly cited.
MgO nanopowders with average size 20 and 40nm were introduced into (Bi
1.6
Pb
0.4
Sr
2
Ca
2
Cu
3
O
10
)(MgO)
x
(=0–0.15 wt.%) in
the pellet form. he optimum amounts for the highest transport critical current density
were = 0.10 and 0.01 wt.% for 20 and
40nm MgO, respectively. hese results were used to fabricate MgO added (Bi, Pb)-2223/Ag sheathed tapes using the powder-in-
tube method. he tapes were sintered at 845
∘
C for 50 h and 100 h. he structure, microstructure, and
of the tapes were determined.
he temperature and magnetic ield dependence of
for the MgO added tapes exhibited a signiicant enhancement compared with
the nonadded tapes.
of 20 nm MgO added tape was higher compared with the 40 nm MgO added tape. A higher
was obtained
when the tapes were sintered for 100 h. he increase in
can be explained as the increase of the lux pinning strength by nanosized
MgO. he nanoparticle with size closer to the coherence length was more efective in enhancing
.
1. Introduction
he transport critical current density
in Bi
1.6
Pb
0.4
Sr
2
Ca
2
Cu
3
O
10
((Bi, Pb)-2223) high temperature superconductor is
limited by the intergrain weak links, grain alignment, and
the weak pinning of lux lines [1–3]. hese factors suppressed
the
and thus prevent the extensive applications of (Bi,
Pb)-2223 superconductor. he weak link is also observed in
silver-sheathed (Bi, Pb)-2223 tape prepared by powder-in-
tube (PIT) technique [4, 5].
Nanoparticles have been used as pinning centers to
improve
(e.g., [6–9]). Pinning center with size larger than
the coherence length was suggested to improve
[10].
However, other studies have suggested that the optimum size
of pinning centers should be comparable to the penetration
depth rather than [11]. he of (Bi, Pb)-2223 system is
2.9 nm and is 60–1000 nm. It is expected that the interaction
between lux line and the nanoparticles will be strong for a
particle with size where << [12].
In previous reports, MgO nanoparticles and nanorods
(with average diameter of 30 nm) have been added into
(Bi,Pb)-2223/Ag tapes [13, 14]. MgO is chemically inert with
(Bi, Pb)-2223, and the transition temperature
did not
change considerably with MgO content. In those reports,
nanosized MgO additions into (Bi, Pb)-2223/Ag tapes have
only been carried out with one average size [13, 14]. It is
interesting to investigate the efect of diferent nanosized
MgO on the critical current density of the (Bi, Pb)-2223
system.
Our initial study on samples in pellet form showed that
at 77 K, Bi
1.6
Pb
0.4
Sr
2
Ca
2
Cu
3
O
10
(MgO)
x
(=0–0.15 wt.%)
pellets exhibited the highest
at = 0.10 wt.% for 20 nm
MgO and = 0.01 wt.% for 40 nm MgO. It is interesting
to study the efect of the two diferent nanosized MgO with
those amounts in (Bi, Pb)-2223(MgO)
x
/Ag tapes. In this
paper, we report on the efect of 20 nm ( = 0.1 wt.%) and
40 nm ( = 0.01 wt.%) MgO in (Bi, Pb)-2223(MgO)
x
/Ag
tapes. We also report the inluence of sintering time (50 and
100 h) on
.
2. Experimental Details
Bi
1.6
Pb
0.4
Sr
2
Ca
2
Cu
3
O
10
superconductor was prepared by the
acetate coprecipitation technique. he powders were calcined
at 730
∘
C for 12 h. Followed by calcination at 845
∘
C for 24 h.