Continuum Mech. Thermodyn. (2014) 26:447–463
DOI 10.1007/s00161-013-0313-x
ORIGINAL ARTICLE
Cs. Mészáros · I. Kirschner · Á. Bálint
Relevance of the time–quasi-polynomials in the classic linear
thermodynamic theory of coupled transport processes
Received: 11 March 2013 / Accepted: 10 July 2013 / Published online: 25 July 2013
© Springer-Verlag Berlin Heidelberg 2013
Abstract A general description of the basic system of ordinary differential equations of coupled transport
processes is given within framework of a linear approximation and treated by tools of matrix analysis and
group representation theory. It is shown that the technique of hyperdyads directly generalizes the method of
simple dyadic decomposition of operators used earlier in the classical linear irreversible thermodynamics and
leads to possible new applications of the concept of quasi-polynomials at descriptions of coupled transport
processes.
Keywords Coupled transport processes · Non-equilibrium thermodynamics · Matrix analysis ·
Group representation theory
1 Introduction
Since the non-equilibrium thermodynamics plays a decisive role [1, 2] in accurate description of the genuine
(usually: coupled) transport processes taking place in macroscopic dissipative continua, the refined mathemat-
ical modeling of such phenomena represents a permanent objective of the contemporary mathematical physics
too. Namely, many transport processes also show features of the anomalous diffusion [3] of non-local charac-
ter and with memory effects on macroscopic level (corresponding usually to the percolative fractal character
on the mesoscopic level), and require, e.g., use of the Riemann–Liouville operators, leading to a widespread
application of the fractional partial derivatives with respect to time and spatial coordinates, as well [4, 5]. The
relevant mathematical features have also been analyzed in detail in studies related to general problems of
fractional diffusion, e.g., [6–9] as well as in [10, 11] where the crucial importance of applying of the theory of
Lie groups in this research field has been pointed out.
The classic domains of the extended irreversible thermodynamics (EIT) have also many open fundamental
questions even in some earlier developed areas of them. It is enough to mention the archetypal problem of
Communicated by Andreas Öchsner.
Cs. Mészáros
Department of Physics and Process Control, Faculty of Mechanical Engineering,
Szent István University, Páter K.u.1. 2103 Gödöll˝ o, Hungary
I. Kirschner
Institute of Physics, Eötvös University, 1117 Budapest, Hungary
Á. Bálint (B )
Department of Chemistry and Biochemistry, Faculty of Agricultural and Environmental Sciences,
Szent István University, Gödöll˝ o, Hungary
E-mail: balint.agnes@mkk.szie.hu