Transport in Porous Media 20: 135-168, 1995. 135 9 1995 KluwerAcademic Publishers. Printed in the Netherlands. Generalized Relative Permeability Coefficients during Steady-State Two-Phase Flow in Porous Media, and Correlation with the Flow Mechanisms D. G. AVRAAM and A. C. PAYATAKES Department of Chemical Engineering, University of Patras, and Institute of Chemical Engineering and High Temperature Chemical Processes, PO Box 1414, GR 26500 Patras, Greece (Received: 7 June 1994; in final form: 14 November 1994) Abstract. A parametric experimental investigation of the coupling effects during steady-state two- phase flow in porous media was carded out using a large model pore network of the chamber- and-throat type, etched in glass. The wetting phase saturation, $1, the capillary number, Ca, and the viscosity ratio, x, were changed systematically, whereas the wettability (contact angle O,), the coalescence factor Co, and the geometrical and topological parameters were kept constant. The fluid flow rate and the pressure drop were measured independently for each fluid. During each experiment, the pore-scale flow mechanisms were observed and videorecorded, and the mean water saturation was determined with image analysis. Conventional relative permeability, as well as generalized relative permeability coefficients (with the viscous coupling terms taken explicitly into account) were determined with a new method that is based on a B-spline functional representation combined with standard constrained optimization techniques. A simple relationship between the conventional relative permeabilities and the generalized relative permeability coefficients is established based on several experimental sets. The viscous coupling (off-diagonal) coefficients are found to be comparable in magnitude to the direct (diagonal) coefficients over board ranges of the flow parameter values. The off-diagonal coefficients (kTij/#j) are found to be unequal, and this is explained by the fact that, in the class of flows under consideration, microscopic reversibility does not hold and thus the Onsager-Casimir reciprocal relation does not apply. The coupling indices are introduced here; they are defined so that the magnitude of each coupling index is the measure of the contribution of the coupling effects to the flow rate of the corresponding fluid. A correlation of the coupling indices with the underlying flow mechanisms and the pertinent flow parameters is established. Key words: two-phase flow, relative permeabilities, ganglion dynamics, viscous coupling, coupling indices. 1 Bo Ca Co Nomenclature = bond number. = capillary number = #1ql/712wl. = coalescence factor (effective probability of coalescence, given a collision between two ganglia in the porous medium). = parameters used in the functional representation of kri in terms of cubic B-splines, (Equation (10a)). = parameters used in the functional representation of k~ij in terms of cubic B-splines, (Equation (10b)).